NUCLEAR TECHNIQUES, Volume. 46, Issue 3, 030605(2023)

In-situ high-temperature NMR spectroscopy and its applications in molten salt ionic structure studies

Huiyan WU1,2, Junheng YINGSU1,2, Yiyang LIU1, Hailong HUANG1, Min GE1, Yuan QIAN1, Xiaobin FU1、*, and Hongtao LIU1、**
Author Affiliations
  • 1Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(7)
    Illustration of the laser heating method used in HT-NMR spectroscopy
    Design drawing of the inner tube of the proposed high-temperature sample cell
    Photos of the complete inner Al2O3 and AlN tubes (a), outer ZrO2 tubes (b), and assembled sample container (c)
    (a) 79Br NMR spectra of the KBr at different laser power, (b) Fitting curve of laser power and temperature
    Temperature fitting curve and average curve of laser power in three experiments using sample container composed of an outer ZrO2 tube and inner AlN tube
    Temperature fitting curve and average curve of laser power using sample container composed of an outer ZrO2 tube and inner BN tube (a) and Al2O3 (b) tube
    35Cl HT-NMR spectra of the LiCl-KCl molten salt in the temperature range of 25 ℃ to 469 ℃
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    Huiyan WU, Junheng YINGSU, Yiyang LIU, Hailong HUANG, Min GE, Yuan QIAN, Xiaobin FU, Hongtao LIU. In-situ high-temperature NMR spectroscopy and its applications in molten salt ionic structure studies[J]. NUCLEAR TECHNIQUES, 2023, 46(3): 030605

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    Paper Information

    Category: Research Articles

    Received: Dec. 1, 2022

    Accepted: --

    Published Online: Apr. 17, 2023

    The Author Email:

    DOI:10.11889/j.0253-3219.2023.hjs.46.030605

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