Acta Optica Sinica, Volume. 42, Issue 14, 1412001(2022)

Improvement of Design of Spectrophotometer for Measuring Fluorescence Color Inter-Instrument Agreement

Mengdan Qin1,3, Guoquan Wang2、*, Kun Yuan1,3、**, Jian Wang3, and Xiang Zhang3
Author Affiliations
  • 1College of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018, Zhejiang , China
  • 2School of Optics and Photonics, Beijing Institute of Technology, Beijing 100081, China
  • 3Hangzhou CHNSpec Technology Co., Ltd., Hangzhou 310034, Zhejiang , China
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    Figures & Tables(19)
    Physical drawings of samples. (a) Fluorescent free samples; (b) samples containing fluorescent substances
    Spectral distributions of samples.(a) Fluorescent free samples; (b) samples containing fluorescent substances
    Inter-instrument agreement between three instruments. (a) Fluorescent free samples; (b) samples containing fluorescent substances
    Relative spectral power distributions of instrument light sources
    Reflectance difference between instruments without fluorescent sample color. (a) KONICA MINOLTA CM-3600A and X-Rite 7000A; (b) KONICA MINOLTA CM-3600A and CHNSpec CS-826; (c) X-Rite 7000A and CHNSpec CS-826
    Reflectance difference between instruments with fluorescent sample color. (a) KONICA MINOLTA CM-3600A and X-Rite 7000A; (b) KONICA MINOLTA CM-3600A and CHNSpec CS-826; (c) X-Rite 7000A and CHNSpec CS-826
    Schematic diagram and physical diagram of integrating sphere. (a) Schematic diagram of integrating sphere; (b) physical diagram of integrating sphere
    Fluorescence regulation device diagram. (a) Structural diagram of adjusting filter; (b) structural diagram of assembly port; (c) schematic diagram of measuring device
    Transmission spectrum curves of filters
    Physical drawing and spectral reflectance of standard calibration plate. (a) Physical drawing of standard calibration plate; (b) spectral reflectance of standard calibration plate
    Inter-instrument agreement varying with displacement
    Inter-instrument agreement between corrected instrument and KONICA MINOLTA CM-3600A.(a) Fluorescent free samples; (b) samples containing fluorescent substances
    Reflectance difference between corrected instrument and KONICA MINOLTA CM-3600A.(a) Fluorescent free samples; (b) samples containing fluorescent substances
    Inter-instrument agreement among CHNSpec CS-826, X-Rite 7000A and corrected instrument.(a) Fluorescent free samples; (b) samples containing fluorescent substances
    Reflectance difference between corrected instrument and CHNSpec CS-826. (a) Fluorescent free samples; (b) samples containing fluorescent substances
    Reflectance difference between corrected instrument and X-Rite 7000A.(a) Fluorescent free samples; (b) samples containing fluorescent substances
    • Table 1. Comparison of basic parameters of three instruments

      View table

      Table 1. Comparison of basic parameters of three instruments

      Parameter

      KONICA MINOLTA

      CM-3600A

      X-Rite 7000ACHNSpec CS-826
      Measuring geometryd/8°d/8°d/8°
      Lighting sourcePulsed xenon lampPulsed xenon lampPulsed xenon lamp and light-emitting diode
      Spectral range /nm360-740360-700360-780
      Wavelength interval /nm101010
      Measuring reflectivity range /%0-2000-2000-200
      Resolution ratio /%0.010.010.01
      RepeatabilityWithin 0.02Within 0.01Within 0.01
      Inter-instrument agreement0.150.080.10
    • Table 2. Color parameters of 12 BCRA color bricks measured by three instruments

      View table

      Table 2. Color parameters of 12 BCRA color bricks measured by three instruments

      Color brick No.

      KONICA MINOLTA

      CM-3600A

      X-Rite 7000ACHNSpec CS-826
      L*a*b*L*a*b*L*a*b*
      188.89-0.701.7788.72-0.721.6288.87-0.591.86
      266.17-1.312.7365.96-1.312.6566.24-1.182.63
      350.28-0.632.2350.03-0.662.2050.39-0.512.07
      427.480.630.2226.760.650.3427.680.410.65
      549.3340.5821.3349.0840.9321.8249.8340.6822.05
      642.4622.279.1042.1522.619.4042.7022.499.15
      758.2334.0536.5858.0334.1037.0658.6033.9037.17
      880.522.1259.4180.351.9559.4380.712.0959.45
      965.03-19.6331.5864.78-19.7431.4764.99-19.5431.14
      1064.35-21.6226.4464.05-21.6931.4764.30-21.5026.01
      1153.21-5.50-25.9252.87-5.36-26.0753.13-5.24-26.14
      1230.774.68-19.3630.134.88-19.5530.994.45-18.91
    • Table 3. Color parameters of 23 fluorescent samples measured by three instruments

      View table

      Table 3. Color parameters of 23 fluorescent samples measured by three instruments

      Fluorescent sample No.

      KONICA MINOLTA

      CM-3600A

      X-Rite 7000ACHNSpec CS-826
      L*a*b*L*a*b*L*a*b*
      196.960.96-5.9796.851.08-6.1098.090.96-7.36
      295.100.28-9.7595.100.63-10.5196.300.31-11.67
      395.221.60-11.5095.201.89-12.0696.401.94-14.16
      494.990.01-9.1894.800.12-9.2796.120.12-10.96
      591.301.74-11.5190.701.72-10.6892.351.94-13.40
      694.341.39-7.3894.191.48-7.6295.411.51-9.24
      793.702.55-14.0793.572.57-13.6894.842.82-16.15
      890.891.78-10.7790.691.93-11.1092.012.01-12.80
      985.0722.21-9.7284.7522.34-9.1685.7222.34-9.62
      10100.35-27.82109.65100.22-28.86108.91106.54-35.26114.55
      1189.35-59.6293.0789.34-61.2692.1194.31-66.6296.10
      1288.4962.3499.2688.8562.65100.2095.0566.18107.31
      1393.88-4.1229.0993.75-4.3129.4094.92-4.1429.14
      1471.0685.6175.5071.3685.9976.4577.9591.0184.13
      1596.482.67-13.1296.322.73-12.9597.492.92-15.04
      1661.7473.60-4.3361.4472.98-4.1766.4877.512.57
      1794.60-20.26108.3094.54-22.76102.6198.92-25.23111.30
      1855.81-22.62-41.3555.09-21.44-41.8456.47-21.77-41.69
      1992.208.4199.5391.417.5298.3094.667.07100.22
      2088.30-9.70-15.3587.63-9.41-15.3988.71-9.32-16.42
      2182.4941.3791.2981.0640.7689.9085.7440.2793.83
      2298.86-22.92103.6798.27-23.46102.19100.81-25.52102.90
      2364.1981.97-9.7663.3580.97-9.6167.5182.57-3.64
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    Mengdan Qin, Guoquan Wang, Kun Yuan, Jian Wang, Xiang Zhang. Improvement of Design of Spectrophotometer for Measuring Fluorescence Color Inter-Instrument Agreement[J]. Acta Optica Sinica, 2022, 42(14): 1412001

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    Paper Information

    Category: Instrumentation, Measurement and Metrology

    Received: Dec. 10, 2021

    Accepted: Jan. 24, 2022

    Published Online: Jul. 15, 2022

    The Author Email: Wang Guoquan (wangguoquan@ei41.com), Yuan Kun (yuankun@cjlu.edu.cn)

    DOI:10.3788/AOS202242.1412001

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