Chinese Journal of Lasers, Volume. 51, Issue 20, 2002306(2024)

Microstructure Evolution and Crack Formation Mechanism of CuSn10/AlSi10Mg Functional Gradient Materials Prepared by Selective Laser Melting

Xin He1,2, Xia Luo1、*, Jingang Tang2, Zhuang Zhao2, Yuhong Dai3, and Bensheng Huang1
Author Affiliations
  • 1School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, Sichuan , China
  • 2Institute of Machinery Manufacturing Technology, China Academy of Engineering Physics, Mianyang 621999, Sichuan , China
  • 3Chengdu Xin Shan Aerospace Technology Co., Ltd., Chengdu 610500, Sichuan , China
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    Figures & Tables(11)
    SLM powder materials and forming process. (a) Morphology of AlSi10Mg powder; (b) distribution of AlSi10Mg powder particle size; (c) morphology of CuSn10 powder; (d) distribution of CuSn10 powder particle size; (e) mass fraction of CuSn10 and AlSi10Mg powders; (f) power distribution of gradient layer; (g) scanning speed distribution of gradient layer
    Physical and microstructure images of FGM samples formed by SLM. (a) Physical image of sample 1; (b) physical image of sample 2; (c) microstructure images of sample 1, illustrated with enlarged view of transition zone and CuSn10 interface region (top right) and local enlarged view (bottom right); (d) microstructure images of sample 2, illustrated with local enlarged view of transition zone (top right) and enlarged view of transition zone and CuSn10 interface region (bottom right)
    SEM images of sample 2 transition zones prepared by SLM
    Schematic diagrams of EDS point position in transition region. (a) Sample 1; (b) mapping resutls of fusion zone at sample 1 interface; (c) sample 2; (d) mapping resutls of fusion zone at sample 2 interface; (e) dot line plot of EDS point scan results corresponding to Cu and Al elements in transition region for sample 1 and sample 2
    XRD patterns and phase diagram calculation results of sample 2. (a) XRD patterns of different transition regions in cross-section of sample 2; (b) Al-Cu-Sn ternary phase diagram at 800 K calculated by CALPHAD; (c) phase molar fraction of vertical cross-section from CuSn10 to AlSi10Mg at 500 K
    Dot line plot and EBSD results of sample 1 and sample 2 in transition region. (a) Dot line plot of physical phase content change in whole transition region; (b) EBSD results in 70%‒80% region
    Analysis results of sample 1 and sample 2. (a)(b) Kernel average misorientation (KAM) maps of 0‒20% AlSi10Mg transition layer area in sample 1; (c)(d) KAM maps of 0‒20% AlSi10Mg transition layer area in sample 2; (e)(f) KAM maps of 80% AlSi10Mg transition layer area in sample 1; (g)(h) KAM maps of 80% AlSi10Mg transition layer area in sample 2; SEM images and EDS results of micro-cracks in 20% AlSi10Mg transition layer area of (i) sample 1 and (j) sample 2; (k) SEM image and EDS result of macro-cracks in 80% AlSi10Mg transition layer area of sample 1; (l) SEM image and EDS result of 80% AlSi10Mg transition layer area of sample 2
    Dot line plots of microhardness distribution in Z-direction of longitudinal section of samples. (a) Sample 1; (b) sample 2
    • Table 1. Chemical composition mass fraction of AlSi10Mg and CuSn10 powders

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      Table 1. Chemical composition mass fraction of AlSi10Mg and CuSn10 powders

      PowderAlSiMgPTiVMnFeNiCuGaSnO
      AlSi10Mg88.60010.7900.3600.0060.0400.0200.0300.1200.0090.0010.02000.110
      CuSn1000.02000.0400000.0200.03091.12008.6700.044
    • Table 2. EDS results at corresponding positions in Figs. 7(i)‒(l)

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      Table 2. EDS results at corresponding positions in Figs. 7(i)‒(l)

      ElementPoint in Figs. 7(i)‒(l) /%
      123456789101112
      Cu59.263.150.689.466.763.348.849.243.563.847.143.7
      Sn28.133.432.47.426.929.740.745.529.526.029.433.7
      Al11.72.214.11.93.25.29.99.924.47.521.121.5
      Si0.80.62.61.23.11.40.60.52.72.72.21.2
      Mg0.10.30.30.10.20.400.20.10.10.30.1
    • Table 3. Physical properties changes generated by Al/Cu intermetallic compound formation

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      Table 3. Physical properties changes generated by Al/Cu intermetallic compound formation

      ReactionVolume change28 /%Atomic percentage of Cu /%Effective enthalpy of formation29 /(kJ/mol)
      Cu+2Al→Al2Cu-0.333-6.76
      9Cu+4Al→Al4Cu9-4.466-5.61
      2 Al2Cu+7Cu→Al4Cu9-4.366-1.15
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    Xin He, Xia Luo, Jingang Tang, Zhuang Zhao, Yuhong Dai, Bensheng Huang. Microstructure Evolution and Crack Formation Mechanism of CuSn10/AlSi10Mg Functional Gradient Materials Prepared by Selective Laser Melting[J]. Chinese Journal of Lasers, 2024, 51(20): 2002306

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    Paper Information

    Category: Laser Additive Manufacturing

    Received: Nov. 6, 2023

    Accepted: Feb. 19, 2024

    Published Online: Oct. 14, 2024

    The Author Email: Luo Xia (winifreed@163.com)

    DOI:10.3788/CJL231366

    CSTR:32183.14.CJL231366

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