NUCLEAR TECHNIQUES, Volume. 48, Issue 1, 010002(2025)

State-of-the-art of the study on ion cyclotron resonance isotope separation

Lanyue LUO, Menglong ZHANG, Yaoting WANG, Heping LI*, Dongjun JIANG, and Mingsheng ZHOU
Author Affiliations
  • Department of Engineering Physics, Tsinghua University, Beijing 100084, China
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    Figures & Tables(10)
    Schematic diagram of ICR-IS facility[21]
    Schematic of the microwave discharge plasma source[22] (a) and structural diagram of the stationary source with crossed fields[25] (b)
    Schematic of the resonant and non-resonant ion trajectories based on the single-particle model[20]
    Schematic diagram of the collecting system of ICR-IS[37]
    Heating efficiency ηvs. heating field frequency for two different ion distributions over longitudinal velocities, for the same mean longitudinal ion velocity U=6×103 m∙s-1, and for electric field E=50 V∙m-1 and effective temperature of longitudinal ion velocity Tz=10 eV[41]
    Experimental and computational results of SIRENA and ERIC devices[44]. (a) Radial variations of the axial Bz(*) and transversal Bt(O) RF magnetic field components in vacuum on the SIRENA device; experimental conditions: frequency fa=384 kHz, antenna current I=100 A, antenna radius r=10.5 cm; calculated values are represented by dashed lines. (b) Mean transverse energy of 44Ca on the ERIC device versus the antenna frequency; energy analyzer measurements (-o-) and Runge-Kutta method calculations (---). (c) Variations of the electric field amplitude |E+|, mean value kz¯ and its width Δkzof the E+(kz) spectrum and width Δf of the resonance with the plasma density at the plasma center (r=0, z=0 m) for the ERIC device
    Curves of the function Fs(v||) with parameters ω=Ωa, u=va, and l=2 m under different magnetic induction intensity (where the digits denote the mass numbers of isotopes)[45](a) B = 1 T, (b) B = 3 T
    • Table 1. Comparisons of major isotope separation methods at the present time[20]

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      Table 1. Comparisons of major isotope separation methods at the present time[20]

      方法Methods基本原理Basic principles主要特点Major characteristics

      气体扩散法

      method

      Gas diffusion

      在分子泄流条件下,质量轻的分子速度较快,通过微孔的概率更大,从而在多孔介质后浓缩

      Under the condition of molecular effusion, lighter molecules move faster and have a higher probability of passing through micropores, thus be concentrated behind the porous medium

      应用时间长,技术比较成熟;要求分离元素具有气态化合物;能耗高,分离级数大

      This technology is mature and has been applied for a long time; the separated elements are required to have their gaseous compounds; the energy consumption is high with a large number of separation stages

      气体离心法

      method

      Gas centrifuge

      在离心力场中,不同质量的物质所受的离心力不同,轻、重组分的气体分别富集在转筒的中心轴和器壁附近

      In the centrifugal force field, substances of different masses experience different centrifugal forces with lighter and heavier gas components being enriched near the central axis and the wall of the rotating cylinder, respectively

      结构成熟,能耗低,寿命长;要求分离元素具有气态化合物The structure of the system is mature with low energy consumption and long service life; the separated elements are required to have their gaseous compounds

      原子蒸气激光同位素分离法

      method

      Atomic vapor laser isotope separation

      根据同位素原子在吸收光谱上的微小差别,利用激光进行选择性激发和电离,再采用外加电磁场将目标同位素离子引出

      Based on the slight difference in the absorption spectrum of the isotope atoms, the target isotope atoms are selectively excited and ionized by a laser with a specific wavelength, and then, the target ions are extracted under an externally applied electromagnetic field

      分离系数高;被分离组分的吸收谱线需要存在同位素位移,需要有满足需求的激光

      This technology has a high separation coefficient; an isotope displacement in absorption spectrum is required for the separated atoms; a laser with specified wavelength and power is also necessary

      电磁法

      Electromagnetic method

      带电粒子在磁场中运动时,质荷比不同的离子会有不同的运动半径,从而在空间上分离

      When charged particles move in the magnetic field, ions with different mass-to-charge ratios will have different motion radii, consequently, being separated from each other spatially

      适用性强,能够分离大部分元素;能耗高,且产量低

      This technology has a good versatility for most elements with a high energy consumption and low output

      化学法

      method

      Chemical

      一定条件下,同一元素的两种化合物相互接触时,该元素中不同同位素在混合物中的分配会发生变化

      Under certain conditions, when two compounds of the same element contact with each other, the distribution of different isotopes within the mixture will change

      能耗低,设备比较简单;单级分离度小,平衡时间长

      This method is applied with a low energy consumption, low single-stage separation coefficient and long equilibrium time

      气体动力学法

      Aerodynamic method

      气体化合物在通过弯曲轨道时,不同质量的同位素会受到不同的离心力

      When gaseous compounds pass through a curved path, isotopes with different masses are subjected to different centrifugal forces

      相比于气体扩散法,单级分离系数高;能耗高

      Compared with gas diffusion method, this approach has a higher single-stage separation coefficient with a high energy consumption

      离子回旋共振法

      method

      Ion cyclotron resonance

      利用特定频率的外加电场对特定种类的离子进行选择性加热,使其具有比其他离子更大的回旋半径,从而实现空间上的分离

      Using an external electric field with specific frequency, a certain type of ions is selectively heated, and thus has a larger cyclotron radius than those of other types of ions, and consequently, leading to the spatial separation

      分离系数高;对电磁场的稳定性、均匀性要求较高

      This method has a high separation coefficient, while simultaneously, there exist high requirements for the stability and uniformity of the electromagnetic field

    • Table 2. Some typical plasma parameters of the ERIC[58]

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      Table 2. Some typical plasma parameters of the ERIC[58]

      参数Parameters数值Values
      最大磁感应强度Magnetic field (max)3 T
      均匀性Homogeneity1%
      均匀区长度Length of homogeneity2 m
      等离子体直径Diameter of the plasma11 cm
      电子温度Electron temperature2~5 eV
      离子温度Ion temperature0.2~2 eV
      离子密度Ion density(1~5)×1011 cm-3
      微波功率Microwave power1 kW
      微波频率Microwave frequency29 GHz
    • Table 3. Part of separation experimental results on ERIC[58]

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      Table 3. Part of separation experimental results on ERIC[58]

      共振同位素

      Resonant isotope

      天然丰度

      Natural abundance / %

      相对质量差

      Relative mass difference / %

      磁场

      Magnetic field / T

      浓缩系数

      Enrichment factor

      贫化系数

      Depletion factor

      43Ca0.1346.860.71411.80.246
      44Ca2.069.051.29180.174
      48Ca0.18616.51.29100.108
      48Ca0.18616.52.0724
      48Ca0.18616.50.723240.335
      64Zn49.84.440.7161.040.263
      68Zn184.951.254.420.63
      110Cd12.42.741.292.650.62
      132Ba0.1044.111.298.50.76
      176Yb12.81.892.9460.92
      50Cr4.354.31.5413.6
      62Ni3.355.490.953.280.96
      102Pd1.034.470.7142.040.94
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    Lanyue LUO, Menglong ZHANG, Yaoting WANG, Heping LI, Dongjun JIANG, Mingsheng ZHOU. State-of-the-art of the study on ion cyclotron resonance isotope separation[J]. NUCLEAR TECHNIQUES, 2025, 48(1): 010002

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    Paper Information

    Category: INVITED REVIEW

    Received: Jun. 15, 2024

    Accepted: --

    Published Online: Feb. 26, 2025

    The Author Email: LI Heping (李和平)

    DOI:10.11889/j.0253-3219.2025.hjs.48.240250

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