Chinese Journal of Liquid Crystals and Displays, Volume. 38, Issue 10, 1305(2023)
Circularly polarized luminescent liquid crystal materials with aggregation-induced emission functionality
Fig. 3. TPE derivatives.(a)Synthesis strategy of coupling first and then modifying;(b)Synthesis strategy of modifying first and then coupling.
Fig. 6. Chemical structural formulas for TPE-C and TPE-SC molecules and mechanism of helical columnar self-assembly for CPL[54]
Fig. 7. Knoevenagel condensation method for synthesizing cyanobiphenyl ethylene
Fig. 8. Schematic diagram of chemical formula of α-8C,α-5C,β-8C and β-5C and their emitting circularly polarized light[62].
Fig. 9. Chemical structure formula of NO2-CS-C6-Chol and its aggregation structure in different phase states [63]
Fig. 10. Chemical structure formulas of DPCE-ECh and DPCE-ACh,and the stacking diagram of DPCE-ECh molecules [64].
Fig. 11. Schematic diagram of CPL enhanced by AIE-FRET effect of CPL-P[65]
Fig. 12. ILC-O molecule columnar stack diagram and ILC-E,ILC-O,ILC-D chemical structure diagram[66].
Fig. 13. Schematic diagram of chiral induction emitting circularly polarized light after adding chiral dopant R/S-BINOL-CN[69]
Fig. 14. Illustration of the formation process of the helix assembly structure of N*-LC,and the molecular structure of dopant NO2-CS-C6-Chol and nematic liquid crystal 5CB[70].
Fig. 15. (a)Illustration of the helical structures of N*-LCs including each chiral dopant with the same(R)- configuration;(b)Molecular structures of binaphthyl derivatives used as dopants and the used liquid crystal;(c)Polarized optical micrograph(POM)images of N*-LC films,Left:0.5% R-1,Right:0.5% R-2 at room temperature[71].
Fig. 16. Schematic diagram of cholesteric liquid crystal with helical structure formed by the co-assembly of chiral dopant(R)-BIN6C-BCN and 5CB[72]
Fig. 17. (a)Schematic diagram of ternary N*-LCs assembly;(b)Structural formula of chiral AIE-active dopant and non-chiral liquid crystal fluorescent polymer[73].
Fig. 18. Energy transfer from GuestA to GuestB leading to CPL enhanced,and schematic diagram of T-N*- LC-3 and its induced CPL behavior[11].
Fig. 19. TPE-PPE chemical structure(a)and photoluminescence spectra of PL-NLC cells composed of NLC-3 and TPE-PPE with concentrations(mass fraction)of 0.1%,0.2%,and 0.5%(b)[74].
Fig. 20. Schematic diagram of the molecular chemical formula of a compound in a polymerizable N*-LC mixture and its self-assembly to form a helical system[75]
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Mao-xin ZHANG, Shi-yi QIAO, Ao ZHANG, Yi FANG, Rui-juan LIAO, Chun-xiu ZHANG, Hai-feng YU. Circularly polarized luminescent liquid crystal materials with aggregation-induced emission functionality[J]. Chinese Journal of Liquid Crystals and Displays, 2023, 38(10): 1305
Category: Research Articles
Received: Jul. 8, 2023
Accepted: --
Published Online: Oct. 25, 2023
The Author Email: Chun-xiu ZHANG (zhangchunxiu@bigc.edu.cn), Hai-feng YU (yuhaifeng@pku.edu.cn)