Journal of Radiation Research and Radiation Processing, Volume. 42, Issue 6, 060206(2024)

In situ synthesis of NiMoO4 cathode with high cycle stability and high specific capacitance for supercapacitors on nickel foam via gamma irradiation

Kai ZHANG1,2, Wei YAN1,2, Maosheng WU1,3, Yiwen LONG1, Fan ZHANG1,2, Hongwei HAN1,4, Xiaolin CHENG1,3, Feng GUO1,4, Zhe XING1,2, Jiangtao HU1,2、**, and Guozhong WU1,2、*
Author Affiliations
  • 1Shanghai Institute of Applied Physics,Chinese Academy of Sciences,Shanghai 201800,China
  • 2University of Chinese Academy of Sciences,Beijing 100049,China
  • 3ShanghaiTech University,Shanghai 14423,China
  • 4Shanghai University,Shanghai 10280,China
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    Figures & Tables(13)
    SEM images (a),(b),EDS-mapping (c) and EDS (d) of 100 kGy-NiMoO4
    SEM images of 20 kGy-NiMoO4 (a),(b),EDS-mapping (c) and EDS (d); SEM images (e),(f),EDS-mapping (g) and EDS (h) of 200 kGy- NiMoO4
    XRD results of x-NiMoO4 sample
    XPS results of x-NiMoO4 sample: Ni 2p (a); Mo 3d (b)
    CV curve (a)~(c) of x-NiMoO4 sample at 2~100 mV/s and comparison curves of all samples at 30 mV/s(d) (color online)
    Dynamic Fitting Process of x-NiMoO4 sample at different scan rate for peak (a)~(d) (color online)
    Pseudocapacitance ratio of 100 kGy-NiMoO4 sample at different scan rates (a)~(e)
    GCD curves (a)~(c) and 3D statistical diagram (d) of x-NiMoO4 sample at 1~15 A/g (color online)
    Nernst curves of x-NiMoO4sample between 0.01 Hz~100 kHz; charge/discharge curve for 10 000 cycles of 100 kGy-NiMoO4 at 10 A/g (b) (color online)
    100 kGy-NiMoO4//AC devices: CV curves under different voltage windows (a); CV curve (b) at different sweep speeds; nernst curve (c); GCD curve (d) under different current densities; statistical chart of specific capacitance (e); comparison of energy density and power density (f) (color online)
    5 000 cycle test curve of 100 kGy-NiMoO4/AC device at 10 A/g current density
    • Table 1. EDS-mapping statistics of 20 kGy-NiMoO4,100 kGy-NiMoO4 and 200 kGy-NiMoO4 (%)

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      Table 1. EDS-mapping statistics of 20 kGy-NiMoO4,100 kGy-NiMoO4 and 200 kGy-NiMoO4 (%)

      原子

      Atom

      20 kGy-

      NiMoO4

      100 kGy-

      NiMoO4

      200 kGy-

      NiMoO4

      O21.9214.7122.98
      Ni46.0352.7840.57
      Mo32.0432.5136.45
    • Table 2. Kinetic fitting parameters,resistance fitting parameters and specific capacitance of x-NiMoO4 sample

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      Table 2. Kinetic fitting parameters,resistance fitting parameters and specific capacitance of x-NiMoO4 sample

      样品

      Sample

      CV拟合面积/10-2

      CV area

      br2paipc/ ACV动力学参数 CV kineticsRs/ ΩRct/ ΩCs / (C·g-1)
      kpcR2pckpaR2pa
      20 kGy-NoMoO41.650.610.9980.0890.014 80.9970.021 70.9990.6625.7500.7
      100 kGy-NoMoO43.310.570.9990.1220.020 30.9990.022 70.9990.6916.8586.1
      200 kGy-NoMoO42.970.520.9990.1190.018 70.9990.018 30.9990.6917.7511.6
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    Kai ZHANG, Wei YAN, Maosheng WU, Yiwen LONG, Fan ZHANG, Hongwei HAN, Xiaolin CHENG, Feng GUO, Zhe XING, Jiangtao HU, Guozhong WU. In situ synthesis of NiMoO4 cathode with high cycle stability and high specific capacitance for supercapacitors on nickel foam via gamma irradiation[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(6): 060206

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    Paper Information

    Category: RADIATION CHEMISTRY

    Received: Oct. 25, 2024

    Accepted: Dec. 7, 2024

    Published Online: Jan. 15, 2025

    The Author Email: Jiangtao HU (胡江涛), Guozhong WU (吴国忠)

    DOI:10.11889/j.1000-3436.2024-0090

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