Acta Optica Sinica, Volume. 44, Issue 4, 0430001(2024)

Prediction Model and Experimental Verification of Reflective Spectra of Responsive Colloidal Crystals

Jinying Zhang1,2、*, Xinye Wang1、**, Yulin Si1, Bingnan Wang1, Jiaxing Yang1, and Yexiaotong Zhang1
Author Affiliations
  • 1Beijing Key Lab for Precision Optoelectronic Measurement Instrument and Technology, School of Optics and Photonics, Beijing Institute of Technology, Beijing 100081, China
  • 2Yangtze Delta Region Academy of Beijing Institute of Technology, Jiaxing 314001, Zhejiang , China
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    Figures & Tables(13)
    Calculation results of relationship between central wavelength of reflection spectrum and filling coefficient based on analytic prediction model
    Finite element prediction model. (a) Schematic diagram of finite element prediction model; (b) 3D finite element prediction model; (c)-(e) cross sectional views of layer A, layer B, and layer C of face centered cubic (111) surface; (f) minimum element finite element prediction model
    Calculation results of reflection spectra of TE wave and TM wave obtained by finite element model
    Calculation results of reflection spectrum based on finite element prediction model. (a) Reflection spectra corresponding to particle refractive index of 2.4, 2.6, and 2.8; (b) reflection spectra corresponding to solvent refractive index of 1.2, 1.4, and 1.6
    Calculation results of reflection spectra based on finite element prediction model
    Calculation results of reflection spectra based on finite element prediction model
    Calculation results of reflection spectra based on finite element prediction model. (a) Reflection spectra corresponding to transversal spacing of 200 nm, 220 nm, and 240 nm; (b) reflection spectra corresponding to longitudinal spacing of 200 nm, 220 nm, and 240 nm
    Calculation results of reflection spectrum and electric field distribution based on finite element prediction model. (a) Reflection spectrum corresponding to different longitudinal spacing when particle diameter is 120 nm; (b) distribution of Hz at wavelength of 680 nm with longitudinal spacing of 224 nm; (c) distribution of Ez at wavelength of 680 nm with longitudinal spacing of 224 nm
    Schematic diagrams of sandwiched electrochromic sample model. (a) Before applying voltage; (b) after applying voltage
    TEM results and HAADF-STEM results of fabricated Fe3O4@SiO2 nanoparticles (all scale bars are 50 nm). (a) TEM image of Fe3O4@SiO2 nanoparticles; (b)-(e) distributions of oxygen, silicon, iron, and their fusion elements under high angle ring dark field scanning transmission electron microscopy
    Test results of prepared sandwiched electrochromic sample. (a) Test photos under 0 V, 2.5 V, and 3.5 V voltages; (b) reflected spectra at 0 V, 2.5 V, and 3.5 V
    • Table 1. Comparison of reported analytical model calculation results with experimental test results

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      Table 1. Comparison of reported analytical model calculation results with experimental test results

      Particle

      Particle

      size D /nm

      Measured

      λ /nm

      λ calculated

      by formula /nm

      Error calculated by formula /%
      Tightly arranged SiO2231454684601.70
      Sulfonated PS241786056080.49
      Fe3O4@SiO225150 (C120S157036606.11
      Fe3O4@SiO225150 (C100S257116863.51
      Fe3O4@SiO2 (this work)120 (C110S56716365.21
    • Table 2. Comparison between calculation results of finite element model and experimental test results

      View table

      Table 2. Comparison between calculation results of finite element model and experimental test results

      Particle

      Particle

      size D /nm

      Measured

      λ /nm

      FEM calculated

      λ /nm

      FEM

      calculated

      error /%

      Formula calculated

      error /%

      Tightly arranged SiO2221454684751.491.70
      Sulfonated PS241786056100.820.49
      Fe3O4@SiO225150 (C120S157037050.286.11
      Fe3O4@SiO225150 (C100S257116801.263.51
      Fe3O4@SiO2 (this work)120 (C110S56716801.345.21
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    Jinying Zhang, Xinye Wang, Yulin Si, Bingnan Wang, Jiaxing Yang, Yexiaotong Zhang. Prediction Model and Experimental Verification of Reflective Spectra of Responsive Colloidal Crystals[J]. Acta Optica Sinica, 2024, 44(4): 0430001

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    Paper Information

    Category: Spectroscopy

    Received: Oct. 20, 2023

    Accepted: Nov. 30, 2023

    Published Online: Feb. 23, 2024

    The Author Email: Zhang Jinying (jyzhang@bit.edu.cn), Wang Xinye (3120205353@bit.edu.cn)

    DOI:10.3788/AOS231682

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