Researching | Progress in Structural Tailoring and Properties of Ternary Layered Ceramics

Journal of Inorganic Materials, Volume. 38, Issue 8, 845(2023)

Progress in Structural Tailoring and Properties of Ternary Layered Ceramics

Haoming DING^1,2,3, Mian LI^1,3, Youbing LI^1,3, Ke CHEN^1,3, Yukun XIAO^1,3, Jie ZHOU⁴, Quanzheng TAO⁴, Rosen Johanna⁴, Hang YIN⁵, Yuelei BAI⁵, Bikun ZHANG⁶, Zhimei SUN⁶, Junjie WANG⁷, Yiming ZHANG^1,3, Zhenying HUANG⁸, Peigen ZHANG⁹, Zhengming SUN⁹, Meikang HAN¹⁰, Shuang ZHAO¹¹, Chenxu WANG¹¹, and Qing HUANG^1,3、*

Author Affiliations

¹1. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

²2. University of Chinese Academy of Sciences, Beijing 101408, China

³3. Qianwan Institute of CHiTECH, Ningbo 315336, China

⁴4. Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-58183, Sweden

⁵5. National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150001, China

⁶6. School of Materials Science and Engineering, Beihang University, Beijing 100191, China

⁷7. School of Materials Science and Engineering, Northwestern Polytechnic University, Xi’an 710072, China

⁸8. School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044, China

⁹9. School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

¹⁰10. Institute of Optoelectronics and Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception, Fudan University, Shanghai 200433, China

¹¹11. State Key Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871, China

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Figures&Tables (28)

References (312)

Paper Information

Figures & Tables(28)

1. Non-exhaustive chronicle of ternary layered materials

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2. Atomic and structural regulation of MAX phases

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3. Different methods for the synthesis of MXene

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4. Structural editing of MAX phases and MXene aided by chemical scissors

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5. Crystal structure and physical properties of novel chalcogenide MAX phases

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6. Preparation of single crystal MAX phases

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7. Heat capacity and anisotropic thermal conductivity in Cr₂AlC single crystals at high temperatures^[110]

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8. i-MAX phases and its derived two-dimensional product of i-MXene^[50]

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9. MAB phases, i-MAB phases and o-MAB phases

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10. Two-dimensional products derived from MAB phases through chemical etching

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$Experimentally measured unilateral notched beam fracture toughness as a function of the weakest to strongest chemical bond stiffness ratio kmin/kmax for some typical ternary layered compounds (MAX and MAB phases)[138]$

11. Experimentally measured unilateral notched beam fracture toughness as a function of the weakest to strongest chemical bond stiffness ratio k_min/k_max for some typical ternary layered compounds (MAX and MAB phases)^[138]

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12. Theoretical calculation of MAB phases

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13. Members and atomic structures of all reported orth- and hex-MBenes^[163]

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14. Discovery of ternary MAX phases

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15. Theoretical study of quaternary MAB phases

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16. Structure mapping based on the selected characteristic quantities of electron concentration and atomic sizes^[36]

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17. MAX-reinforced metal matrix composites

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18. SEM images of a Sn whisker alternately cultivated in air and vacuum^[259]

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$SEM images of fractured Zr2InC surface and an In whisker[243]$

19. SEM images of fractured Zr₂InC surface and an In whisker^[243]

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20. Microstructure of Sn whiskers/Ti₂SnC interface^[266]

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21. (a) Electrical conductivity of different MXene films and (b) conductivity-dependent electromagnetic interference shielding effectiveness of different MXenes^[282]

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22. Defect generation and microstructural transformation in MAX phase materials under irradiation

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23. MAX phase irradiation temperature effect

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24. Phase transformation and amorphization caused by irradiation of MAX phases^[302]

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25. STEM micrographs of (Mo_2/3RE_1/3)₂GaC i-MAX phase along (a) [100] and (b) [010] zone axis^[120]

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Table 1. List of synthesized i-MAX phases

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Table 1. List of synthesized i-MAX phases

M′_4/3	M″_2/3	A	X	Ref.
Mo_4/3	Sc_2/3/Y_2/3	Al	C	[50,118]
W_4/3	Sc_2/3/Y_2/3	Al	C	[123]
Mn_4/3	Sc_2/3	Ga	C	[124]
Cr_4/3	Sc_2/3/Y_2/3/Zr_2/3	Al	C	[125-126]
Cr_4/3	Sc_2/3	Ga	C	[16,124]
V_4/3	Sc_2/3/Zr_2/3	Al	C	[118,127]
Mo_4/3	Sc_2/3/Y_2/3	Ga	C	[128]
Mo_4/3	Ce_2/3/Pr_2/3/Nd_2/3/Sm_2/3/Gd_2/3/Tb_2/3/Dy_2/3/Ho_2/3/Er_2/3/Tm_2/3/Lu_2/3	Al	C	[119]
Mo_4/3	Gd_2/3/Tb_2/3/Dy_2/3/Ho_2/3/Er_2/3/Tm_2/3/Yb_2/3/Lu_2/3	Ga	C	[120]
W_4/3	Gd_2/3/Tb_2/3/Dy_2/3/Ho_2/3/Er_2/3/Tm_2/3/Lu_2/3	Al	C	[121]
Cr_4/3	Gd_2/3/Tb_2/3/Dy_2/3/Ho_2/3/Er_2/3/Tm_2/3/Lu_2/3	Al	C	[122]

Table 2. Stable MAB phases by theoretical prediction

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Table 2. Stable MAB phases by theoretical prediction

MAB phase	M type	A type	Ref.	MAB phase	M type	A type	Ref.
Orthorhombic M₂A₂B₂	Ti	Al	[160-161]	Orthorhombic M₃AB₄	Sc	Al	[160-161]
	Hf				Ti
	V				Zr
	Nb				Hf
	Ta				V
	Tc				Nb
	Cr				Ta
	Mn				Mo
Orthorhombic M₂AB₂	Sc	Al	[160-161]		W
	Ti				Mn
	Zr				Fe
	Hf			Orthorhombic M₄AB₆	Sc	Al	[160-161]
	V				Ti
	Nb				Zr
	W				Hf
	Tc				V
	Rh				Nb
	Ni				Ta
	Co				Mo
Orthorhombic M₃A₂B₂	Sc	Al	[160-161]	Hexagonal M₂AB₂	Ti	Sn	[52]
	Ti				Hf	In	[162]
	Zr				Hf	Sn
	Hf				Zr	In
	Cr					Pb
	Mn					Tl
	Tc			Hexagonal M₃AB₄	Hf	In	[162]
	Fe					Sn
	Ni					P
					Zr	Cd
					Zr	Pb

Table 3. Theoretical mechanical properties of several MAB-phases, including bulk modulus (B), shear modulus (G), Young’s modulus (E), and Poisson ratio (ν)

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Table 3. Theoretical mechanical properties of several MAB-phases, including bulk modulus (B), shear modulus (G), Young’s modulus (E), and Poisson ratio (ν)

MAB phase	B/GPa	G/GPa	E/GPa	¯ν/GPa	Ref.
Mn₂AlB₂	239	169	411	0.21	[160]
Fe₂AlB₂	209	133	329	0.24
Co₂AlB₂	216	92	242	0.31
TiAlB	145	116	274	0.18
VAlB	173	133	317	0.19
NbAlB	180	130	315	0.21
TaAlB	192	138	333	0.21
CrAlB	189	140	338	0.20
MnAlB	167	101	252	0.25
TcAlB	220	114	292	0.28
Sc₂AlB₂	238	142	356	0.25
Ti₂AlB₂	170	150	347	0.16
Zr₂AlB₂	152	112	270	0.20
Hf₂AlB₂	168	132	314	0.19
V₂AlB₂	195	129	317	0.23
Nb₂AlB₂	199	110	279	0.27
Cr₂AlB₂	229	177	422	0.19
Mo₂AlB₂	238	142	356	0.25
W₂AlB₂	262	139	354	0.28
Tc₂AlB₂	260	132	339	0.28
Ni₂AlB₂	200	91	237	0.30
MoAlB	213	146	357	0.22	[164]
WAlB	232	146	362	0.24	[164]
Mn₂AlB₂	222	161	388	0.21	[165]
Fe₂AlB₂	210	132	329	0.24	[165]
Co₂AlB₂	241	101	266	0.31	[166]
Zr₃CdB₄	—	82	202	0.37	[167]
Hf₃PB₄	—	180	407	0.19	[168]

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Haoming DING, Mian LI, Youbing LI, Ke CHEN, Yukun XIAO, Jie ZHOU, Quanzheng TAO, Rosen Johanna, Hang YIN, Yuelei BAI, Bikun ZHANG, Zhimei SUN, Junjie WANG, Yiming ZHANG, Zhenying HUANG, Peigen ZHANG, Zhengming SUN, Meikang HAN, Shuang ZHAO, Chenxu WANG, Qing HUANG. Progress in Structural Tailoring and Properties of Ternary Layered Ceramics[J]. Journal of Inorganic Materials, 2023, 38(8): 845

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Paper Information

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Received: Mar. 9, 2023

Accepted: --

Published Online: Dec. 28, 2023

The Author Email: Qing HUANG (huangqing@nimte.ac.cn)

DOI:10.15541/jim20230123

Topics

laser devices and laser physics

Lasers and Laser Optics

laser manufacturing

Instrumentation, Measurement and Metrology