Matter and Radiation at Extremes, Volume. 9, Issue 2, 027401(2024)

High-pressure minerals and new lunar mineral changesite-(Y) in Chang’e-5 regolith

Jing Yang1 and Wei Du2,3、a)
Author Affiliations
  • 1Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
  • 2State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences (CAS), Guiyang 550081, China
  • 3CAS Center for Excellence in Comparative Planetology, Hefei 230026, China
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    Figures & Tables(5)
    Backscattered electron (BSE) image of the seifertite- and stishovite-bearing silica fragment in CE-5 regolith sample 01GP. The phase in the smooth area around the seifertite, stishovite, and α-cristobalite-like phases is amorphous silica. Sft, seifertite; Sti, stishovite; α-Crs-like, α-cristobalite-like. Reproduced with permission from Pang et al., “New occurrence of seifertite and stishovite in Chang’E-5 regolith,” Geophys. Res. Lett. 49(12), e2022GL098722 (2022). Copyright 2022 John Wiley & Sons.
    BSE images showing the tweed-like texture of the silica fragment in Fig. 1. The white dashed lines represent the orientations of the amorphous silica lamellae. Sft, seifertite; Sti, stishovite; α-Crs-like, α-cristobalite-like. Reproduced with permission from Pang et al., “New occurrence of seifertite and stishovite in Chang’E-5 regolith,” Geophys. Res. Lett. 49(12), e2022GL098722 (2022). Copyright 2022 John Wiley & Sons.
    Y+REE vs other cations in changesite-(Y), expressed as cations per 56 O atoms. Data are listed in Table I. (a) Y+REE vs Ca; the regression equation is for the line shown, fitted to the changesite-(Y) grains in CE-5 sample 01GP. (b) Y+REE vs Na, Si, and Mg,Fe-site atoms in changesite-(Y). Mg,Fe-site atoms include Mg, Fe, and Mn.
    BSE images of changesite-(Y) in basalt fragments from CE-5 regolith sample 01GP. Fa, fayalite; Px, pyroxene; Pl, plagioclase; Crs, cristobalite; Bdy, baddeleyite; Tro, troilite.
    • Table 1. Changesite-(Y) compositions in CE-5 regolith sample 01GP.a

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      Table 1. Changesite-(Y) compositions in CE-5 regolith sample 01GP.a

      No. 1No. 2No. 3No. 4No. 5No. 6No. 7No. 8No. 9No. 10No. 11No. 12No. 13No. 14No. 15No. 16No. 17
      P2O542.8542.7442.4340.1739.0838.941.740.641.142.540.740.239.741.041.241.240.0
      SiO20.140.281.364.027.616.270.351.760.750.341.421.231.550.480.500.560.90
      TiO20.020.050.03n.a.n.a.n.a.n.a.n.a.0.040.060.050.020.06b.d.0.020.030.04
      Al2O30.070.080.20n.a.n.a.n.a.n.a.n.a.0.080.040.47b.d.0.07b.d.b.d.b.d.0.02
      FeO6.326.466.236.106.046.036.597.776.776.777.256.336.496.066.036.236.13
      MnO0.110.090.060.060.050.070.070.110.040.060.050.060.060.050.050.060.06
      MgO0.330.330.320.150.100.11b.d.0.030.350.300.350.060.050.02b.d.0.05b.d.
      CaO40.7641.0240.7638.0937.2838.037.937.538.641.638.436.937.438.137.737.437.3
      BaO0.030.04b.d.n.a.n.a.n.a.n.a.n.a.0.03b.d.b.d.b.d.b.d.0.02b.d.b.d.0.03
      Na2O0.320.480.360.180.100.140.020.120.100.370.240.040.020.060.06b.d.b.d.
      K2O0.150.180.28n.a.n.a.n.a.n.a.n.a.0.020.040.030.040.090.040.060.040.05
      Y2O31.681.451.592.212.002.192.762.622.741.452.022.962.762.452.412.122.44
      La2O30.890.740.761.181.091.091.421.271.270.690.971.982.001.801.802.262.19
      Ce2O32.141.921.892.862.662.593.463.282.981.752.474.414.424.304.184.774.79
      Pr2O30.2800.1890.2390.3410.2860.2440.4240.3100.3430.2580.3020.5770.6340.5810.5570.4990.550
      Nd2O31.3081.0661.2571.6821.5821.5022.0521.9251.9851.1241.5912.5082.2822.4202.4382.3862.384
      Sm2O30.3010.2740.272n.a.n.a.n.a.n.a.n.a.0.4890.3150.3740.5780.5850.5630.5940.5400.553
      Gd2O30.4590.5000.3730.6360.5850.6230.8280.7660.7830.2870.5160.7910.6600.7370.7310.5070.779
      Dy2O30.4200.2950.3010.5360.4450.5580.6320.5350.5470.2710.3500.6590.4440.4130.4280.3460.647
      Total98.698.298.798.298.998.398.298.699.298.397.899.499.499.098.899.098.9
      (Y+REE)2O37.476.436.689.458.658.7911.5710.7111.146.148.5914.4613.7913.2713.1413.4314.32
      P13.9613.9213.7013.1312.4912.6113.9113.4813.6813.8613.5713.5013.3313.7313.8113.8013.55
      Si0.0550.1080.5201.5532.8732.3990.1370.6900.2930.1320.5600.4880.6140.1910.1970.2220.360
      Sum (P,Si)14.0214.0314.2214.6815.3615.0114.0514.1713.9714.0014.1313.9813.9513.9214.0114.0213.91
      Ti0.0050.0140.0070.0000.0000.0000.0000.0000.0130.0180.0150.0070.0170.0000.0050.0080.011
      Al0.0290.0340.0880.0000.0000.0000.0000.0000.0390.0200.2160.0060.0320.0030.0050.0070.009
      Fe2.0352.0771.9861.9691.9081.9312.1712.5492.2252.1842.3892.1002.1502.0051.9962.0622.048
      Mn0.0350.0280.0200.0190.0170.0230.0230.0360.0130.0210.0150.0180.0200.0160.0180.0200.020
      Mg0.1870.1880.1840.0840.0550.0620.0000.0170.2030.1740.2050.0330.0310.0140.0000.0320.008
      Ca16.8116.9116.6515.7615.0715.5816.0215.7516.2417.1716.1815.6915.9116.1515.9715.8615.98
      Ba0.0040.0050.0000.0000.0000.0000.0000.0000.0040.0000.0000.0000.0000.0030.0000.0000.004
      Na0.2380.3570.2680.1350.0720.1000.0140.0900.0730.2790.1860.0340.0120.0420.0420.0000.000
      K0.0750.0870.1350.0000.0000.0000.0000.0000.0120.0220.0170.0210.0450.0220.0300.0180.026
      Y+REE1.140.981.021.451.301.351.821.681.750.951.352.262.152.062.032.062.22
      Sum of20.5620.6820.3619.4218.4319.0520.0520.1220.5820.8320.5720.1720.3720.3120.1020.0720.33
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    Jing Yang, Wei Du. High-pressure minerals and new lunar mineral changesite-(Y) in Chang’e-5 regolith[J]. Matter and Radiation at Extremes, 2024, 9(2): 027401

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    Paper Information

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    Received: Mar. 2, 2023

    Accepted: Nov. 9, 2023

    Published Online: Apr. 15, 2024

    The Author Email: Du Wei (duwei@mail.gyig.ac.cn)

    DOI:10.1063/5.0148784

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