Journal of Inorganic Materials, Volume. 39, Issue 8, 911(2024)

High Stability/Catalytic Activity Co-based Perovskite as SOFC Anode: In-situ Preparation by Fuel Reducing Method

Jianlong PAN... Guanjun MA, Lemei SONG, Yu HUAN* and Tao WEI* |Show fewer author(s)
Author Affiliations
  • School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
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    Figures & Tables(18)
    XRD patterns of SCMO and SVCMO before and after calcination under different conditions
    Microstructure of R-SVCMO sample
    Thermal expansion of different materials
    XPS spectra for SCMO and R-SVCMO
    Conductivity and H2-TPR curves for SCMO and R-SVCMO in testing H2
    Electrochemical performance of single cells with SCMO and R-SVCMO as anode materials
    Electrochemical performance of single cells or symmetric cells with SCMO and R-SVCMO as anodes or symmetric electrodes
    Electrochemical performance of single cells with SCMO and R-SVCMO as anodes in CH4 atmosphere
    ietveld refined XRD patterns of (a) SCMO and (b) R-SVCMO
    XRD patterns of SVCMO and D-SVCMO composite anodes
    O1s XPS spectra for SVCMO and SCMO samples
    XRD patterns of SVCMO and LSGM after co-firing in air for 5 h
    XRD patterns of SVCMO and SDC after co-firing in air for 5 h
    XRD pattern of LSCF
    SEM image of the single cell with R-SVCMO anode
    Equivalent circuit for the fitting EIS of different cells
    • Table 1. Lattice parameters of SCMO and R-SVCMO obtained by XRD Rietveld refinement

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      Table 1. Lattice parameters of SCMO and R-SVCMO obtained by XRD Rietveld refinement

      ParameterSCMOR-SVCMO
      Space groupI4/mI4/m
      a=b5.63745.6218
      c7.91287.8823
      α/(º)9090
      β/(º)9090
      γ/(º)9090
      Sr-O/Å2.81302.8071
      Co-O/Å2.07652.0532
      V-O/Å1.7758
      Mo-O/Å1.89451.9191
    • Table 2. Area content percentages of Mo and Co elements in different valences, and different O types for SCMO and R-SVCMO samples based on XPS data

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      Table 2. Area content percentages of Mo and Co elements in different valences, and different O types for SCMO and R-SVCMO samples based on XPS data

      SampleValence ratio/%
      MoOCo
      Mo5+Mo6+Olatt.Oad.H2OCo2+Co3+
      SCMO34.165.931.460.58.274.026.0
      R-SVCMO58.541.531.165.53.462.937.1
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    Jianlong PAN, Guanjun MA, Lemei SONG, Yu HUAN, Tao WEI. High Stability/Catalytic Activity Co-based Perovskite as SOFC Anode: In-situ Preparation by Fuel Reducing Method [J]. Journal of Inorganic Materials, 2024, 39(8): 911

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    Paper Information

    Category:

    Received: Jan. 11, 2024

    Accepted: --

    Published Online: Dec. 12, 2024

    The Author Email: HUAN Yu (mse_huany@ujn.edu.cn), WEI Tao (mse_weit@ujn.edu.cn)

    DOI:10.15541/jim20240025

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