Journal of Inorganic Materials, Volume. 35, Issue 7, 769(2020)

Application of Conductive Metal Organic Frameworks in Supercapacitors

Zehui LI1... Meijuan TAN2, Yuanhao ZHENG3, Yuyang LUO3, Qiushi JING3, Jingkun JIANG1 and Mingjie LI4,* |Show fewer author(s)
Author Affiliations
  • 1State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
  • 2Nanjing University of Information Science and Technology, Nanjing 210044, China
  • 3School of Environmental Science and Engineering, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • 4CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Biomass Energy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
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    Figures & Tables(9)
    Representation of possible modes of charge transport in MOFs: (a) hopping charge transport, (b) through-space charge transport, and (c) through-bond charge transport[22]
    Control strategy of conductive MOFs in supercapacitors From microstructure, active site, surface interface and nanocomposite of conductive MOFs to energy storage applications
    (a) Crystal structure of Cu-CAT viewed along the c-axis; (b) Structure of the solid-state supercapacitor (left) and photograph of a red light-emitting-diode powered by the three supercapacitors connected in series (right); (c, d) SEM and photographic images (inset in (d)) of the Cu-CAT NWAs growing on carbon fiber paper; Performance comparison of (e)Cu-CAT NWAs and (f) MOF materials, and carbon materials based symmetric solid-state supercapacitors[29]
    (a) Molecular structure of Ni3(HITP)2; (b) Relative size of pores, electrolyte Et4N+ and BF4- ions, and acetonitrile solvent molecules showing in a space-filling diagram of idealized Ni3(HITP)2; (c) Comparison of areal capacitance for various materials normalized relative to their BET surface areas[30]
    Structure of MOF‐867 and performance of the nMOF SCs[44]
    Cycle performance for all Ni-DMOFs-based asymmetric supercapacitor at a current density of 10 A∙g-1[41]
    Schematic diagram for coin-type supercapacitors[44]
    (a) Illustration of the synthesis methodology for polyaniline-ZIF-67 on carbon cloth; (b) Areal capacitances of the PANI-ZIF-67-CC and other electrode materials; (c-f) Schematic illustrations of PANI-ZIF-67-CC flexible solid-state SC device; (g) Photograph of a red light-emitting-diode (LED) powered by the three SCs connected in series[52]
    • Table 1. MOFs with different center metal atoms for SCs

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      Table 1. MOFs with different center metal atoms for SCs

      MetalOrganic ligandMOFsConductivity/(S∙m-1)SBET/(m2·g-1)Specific capacitanceEnergy densityPower densityRef.
      Fe1,3,5-Benzenetricarboxylic acid (H3BT)CMIL-100--39 F·g-1--[35]
      CoPolyethylene glycol (PEG)Co-MOF-71--206.76 F·g-17.18 Wh·kg-1-[36]
      CoBenzendicarboxylic (BDC) acidCo-BDC-9.09131.8 F·g-120.7 Wh·kg-13880 W·kg-1[25]
      Co2,6-Naphthalenedicarboxylic (NDC) acidCo-NDC-20.29147.3 F·g-123.1 Wh·kg-15490 W·kg-1[25]
      Co4,4-Biphenyldicarboxylic (BPDC) acidCo-BPDC-138.35179.2 F·g-131.4 Wh·kg-15640 W·kg-1[25]
      NiIsonicotinic acidNi-MOF-148634 F·g-1--[37]
      NiSalicylate ion1D Ni-MOF-186.81698 F·g-1--[38]
      Nip-Benzenedicarboxylic acid (PTA)Ni-MOF-24--1127 F·g-119.17 Wh·kg-11750 W·kg-1[39]
      Ni1,3,5-Benzenetricarboxylic (btc) acid (H3BT)CNi3(btc)2·12H2O--726 F·g-116.5 Wh·kg-12078 W·kg-1[40]
      Ni9,10-Anthracenedicarboxylic acid (ADC)Ni-DMOF-ADC-783552 F·g-1--[41]
      Ni2,3,6,7,10,11-Hexaiminotriphenylene (HITP)Ni3(HITP)2>5000630111 F·g-1--[30]
      Zn4,4’-Biphenyldicarboxylic acid (H2BPC)Zn6(BPC)6(L)3·9DMF--23 F·g-11.9 Wh·kg-13 W·kg-1[42]
      Znp-Phenylenediamine (pPDA)Zn-(pPDA)MOF0.1~1.05200.86 F·g-162.8 Wh·kg-14500 W·kg-1[43]
      Cd2,5-Thiophenedicarboxylic acid (H2TDC)Cd2(TDC)2(L)2·2H2O--22 F·g-12.1 Wh·kg-13.3 W·kg-1[42]
      Zr2,2’-Bipyridine-5,5’-dicarboxylate (BPYDC)nMOF-867--5.085 mF·cm-26.04×10-4 Wh·cm-3stack1.097 W·cm-3stack[44]
      Zn, Nip-Benzenedicarboxylic acid (PTA)Zn-dopedNi-MOF--1620 F·g-127.56 Wh·kg-11750 W·kg-1[45]
      Co, ZnBenzendicarboxylic acidCo8-MOF-5-29000.49 F·g-1--[46]
      Zn, ZrTerephthalic acidHP-UiO-66--849 F·g-132 Wh·kg-1240 W·kg-1[47]
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    Zehui LI, Meijuan TAN, Yuanhao ZHENG, Yuyang LUO, Qiushi JING, Jingkun JIANG, Mingjie LI. Application of Conductive Metal Organic Frameworks in Supercapacitors[J]. Journal of Inorganic Materials, 2020, 35(7): 769

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    Paper Information

    Category: REVIEW

    Received: Aug. 16, 2019

    Accepted: --

    Published Online: Mar. 3, 2021

    The Author Email: LI Mingjie (limj@qibebt.ac.cn)

    DOI:10.15541/jim20190433

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