Acta Optica Sinica, Volume. 43, Issue 24, 2430001(2023)

Broadband Cavity-Enhanced Atmospheric Nitrogen Dioxide Detection Technology Based on High-Precision Proportional Integral Derivative Temperature Control

Xinyu Xu1,2, Jiacheng Zhou2、*, Zheng Liu2, Qunting Yang2, Xuezhe Xu2, Weixiong Zhao2, and Weijun Zhang1,2
Author Affiliations
  • 1School of Environmental Science and Optoelectronic Technology, University of Science and Technology of China, Hefei 230026, Anhui , China
  • 2Anhui Institute of Optics and Fine Mechanics, Hefei Institute of Materials Science, Chinese Academy of Sciences, Hefei 230031, Anhui , China
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    Figures & Tables(10)
    Structure diagram of high-precision miniaturized BBCEAS system based on LED light source
    Diagram of influence of LED temperature drift. (a) Variation of LED light intensity with temperature; (b) variation of 460 nm light intensity with temperature and fitting diagram
    Control flow chart of PID adjustment algorithm based on Kalman filter
    Flow chart of self-tuning PID parameter program
    LED temperature control diagram before and after PID algorithm improvement. (a) Comparison of LED temperature control effect before and after PID improvement; (b) comparison of changes of light intensity fluctuation and temperature control adjustment accuracy after LED temperature control stabilization
    Mirror reflectivity calibration. (a) Mirror reflectivity calibration curve; (b) cavity loss (solid line) and effective path length (dashed line)
    Instrument performance evaluation comparison diagram. (a) Comparison diagram of concentration changing with time series; (b) comparison diagram of variance changing with average time; (c) comparison diagram of frequency distribution Gaussian linear fitting
    Accuracy evaluation. (a) Comparison of test results of different concentrations of NO2; (b) linear relationship between preset concentration and measured concentration
    Real-time atmospheric measurement. (a) Comparison of real-time atmospheric measurements; (b) correlation of measurement results of BBCEAS
    • Table 1. Comparison of detection accuracy between BBCEAS instrument and other methods

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      Table 1. Comparison of detection accuracy between BBCEAS instrument and other methods

      Measurement techniqueLimit of detection /(10-91σIntegration time /minYearReference
      LIF0.094120014
      FTIR2.5520145
      DOAS0.152-1520056
      CRDS0.04(d=70 cm,Leff=20 km)1202028
      CAPS0.191(d=96 cm,Leff=4.8 km)1202029
      BBCEAS0.05(d=42 cm,Leff=2.26 km)1201715
      0.018(d=84 cm,Leff=4.2 km)1.6201913
      0.2(d=101 cm,Leff=5 km)5202011
      0.14(d=68 cm,Leff=3.4 km)1202029
      0.021(d=31cm,Leff=2.07 km)12022This work
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    Xinyu Xu, Jiacheng Zhou, Zheng Liu, Qunting Yang, Xuezhe Xu, Weixiong Zhao, Weijun Zhang. Broadband Cavity-Enhanced Atmospheric Nitrogen Dioxide Detection Technology Based on High-Precision Proportional Integral Derivative Temperature Control[J]. Acta Optica Sinica, 2023, 43(24): 2430001

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    Paper Information

    Category: Spectroscopy

    Received: Feb. 6, 2023

    Accepted: Mar. 22, 2023

    Published Online: Dec. 12, 2023

    The Author Email: Zhou Jiacheng (zhoujch@aiofm.ac.cn)

    DOI:10.3788/AOS230511

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