Journal of Inorganic Materials, Volume. 37, Issue 7, 697(2022)

Two-dimensional Transition Metal Dichalcogenides for Electrocatalytic Oxygen Reduction Reaction

Lian SUN... Quanchao GU, Yaping YANG, Honglei WANG, Jinshan YU and Xingui ZHOU* |Show fewer author(s)
Author Affiliations
  • Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
  • show less
    Figures & Tables(11)
    Structures and crystal forms of 2D TMDs
    Calculated band structures of (a) bulk MoS2, (b) quadrilayer MoS2, (c) bilayer MoS2, and (d) monolayer MoS2[26]
    Designing strategy for ORR catalysts[3,41]
    M-position doping for 2D TMDs[53,55]
    X-position doping of 2D TMDs[45,61]
    (a) Preparative schematic illustration by phase conversion from 2H-MoS2, (b) ORR polarization curves in 0.1 mol·L-1 KOH, and (c) corresponding K-L plots of 1T-MoS2[68]
    Defect and strain engineering of 2D TMDs[46,49,65]
    2D TMDs@carbon materials heterostructure ORR catalysts[85,92]
    Other 2D TMDs-based heterostructure ORR catalysts[88⇓-90]
    • Table 1. Properties of typical 2D TMDs-based ORR catalysts

      View table
      View in Article

      Table 1. Properties of typical 2D TMDs-based ORR catalysts

      CatalystElectrolyteOnset potential / V (vs. RHE) Half-wave potential / V (vs. RHE) Electrons transfer number, nRef.
      P-MoS2-0.2 0.1 mol·L-1 KOH 0.960.803.60[45]
      I-PdSe2-50 0.1 mol·L-1 KOH -0.763.67[46]
      Ag/MoS20.1 mol·L-1 KOH 0.900.833.98[47]
      2H+1T-FeSe@NC1.0 mol·L-1 KOH 0.970.803.90[48]
      O-MoS2-87 0.1 mol·L-1 KOH 0.940.803.49[49]
    • Table 2. Properties of typical 2D TMDs heterostructures-based ORR catalysts

      View table
      View in Article

      Table 2. Properties of typical 2D TMDs heterostructures-based ORR catalysts

      CatalystElectrolyteOnset potential / V (vs. RHE) Half-wave potential / V (vs. RHE) Electrons transfer number, nRef.
      Pt/MoS2-rGO 0.1 mol·L-1 HClO40.900.80-[85]
      MoS2-CNT 0.1 mol·L-1 KOH 0.65-~4.00[86]
      MoS2/S-PC 0.5 mol·L-1 H2SO4-0.864.00[87]
      Ni3S2/MoS20.1 mol·L-1 KOH 0.950.883.99[88]
      hBN-MoS20.1 mol·L-1 KOH 0.800.604.00[89]
      FePc-MoS20.1 mol·L-1 KOH -0.894.00[90]
    Tools

    Get Citation

    Copy Citation Text

    Lian SUN, Quanchao GU, Yaping YANG, Honglei WANG, Jinshan YU, Xingui ZHOU. Two-dimensional Transition Metal Dichalcogenides for Electrocatalytic Oxygen Reduction Reaction[J]. Journal of Inorganic Materials, 2022, 37(7): 697

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: REVIEW

    Received: Mar. 8, 2022

    Accepted: --

    Published Online: Jan. 10, 2023

    The Author Email: ZHOU Xingui (zhouxinguilmy@163.com)

    DOI:10.15541/jim20220128

    Topics