Journal of Inorganic Materials, Volume. 38, Issue 7, 815(2023)
Figures & Tables(13)
1. Laser-induced skutterudite SHS reaction process at room temperature
2. (a) Schematic diagram of room temperature and preheating SHS experiment; (b) Physical picture of the preheating module; (c-h) I. combustion wave front (t =0.95 s) and II. section photographs of powders compacts after SHS for sample Px (x =150, 200, 250, 300, 350, 400); (i) Trend graph of combustion temperature and combustion velocity changed with power density of ignition laser in CoSb3 system
3. Four typical SHS performances in CoSb3 system with different preheating temperatures
4. (a) Trend graph of combustion temperature changed with preheating temperature in CoSb3 system and (b) variation trend of combustion rate around region 3
5. XRD patterns of compact powders after SHS in different preheating temperature ranges
S3. Time-dependent temperature graphs of sample Px at the thermocouple TC1 (black) and TC2 (red)
S4. Time-dependent temperature graphs of sample Tx (x =150, 160, 170, 200, 210, 220, 230, 240, 250, 330, 350, 380, 400) at the thermocouple TC1 (black) and TC2 (red)
S5. SE, BSE images ((a, c)×200, (b, d) ×5000) of (a, b) sample P300 and (c, d) sample T400
Table 1. Laser ignition process for SHS samples at room temperature
View tableView in ArticleTable 1. Laser ignition process for SHS samples at room temperature
Sample Ignition time, t/s Laser power, P/W Scan rate, vL/ (mm·s-1) Scan spacing, d/mm Energy density, η/(J·mm-2) RT6.25 0.81 500 800 0.10 6.25 RT12.5 1.31 500 400 0.10 12.5 RT25 2.56 500 400 0.05 25
Table 2. Laser ignition process of SHS samples under preheating condition
View tableView in ArticleTable 2. Laser ignition process of SHS samples under preheating condition
Sample Preheating temperature, T/℃ Ignition time, t/s Laser power, P/W Energy density, η/(J·mm-2) Sample Preheating temperature, T/℃ Ignition time, t/s Laser power, P/W Energy density, η/(J·mm-2) P150 300 0.95 150 1.88 T210 210 0.95 300 3.75 P200 300 0.95 200 2.50 T220 220 0.95 300 3.75 P250 300 0.95 250 3.13 T230 230 0.95 300 3.75 P300 300 0.95 300 3.75 T240 240 0.95 300 3.75 P350 300 0.95 350 4.38 T250 250 0.95 300 3.75 P400 300 0.95 400 5.00 T330 330 0.95 300 3.75 T150 150 0.95 300 3.75 T350 350 0.95 300 3.75 T160 160 0.95 300 3.75 T380 380 0.95 300 3.75 T170 170 0.95 300 3.75 T400 400 0.95 300 3.75 T200 200 0.95 300 3.75
Table 3. Area scanning and spot scanning results (Atomic percent) of samples P300 and T400
View tableView in ArticleTable 3. Area scanning and spot scanning results (Atomic percent) of samples P300 and T400
Sample P300 (Fig. S5(a)) Sample T400 (Fig. S5(c)) Area Co/% Sb/% Area Co/% Sb/% Area a1 18.24 81.76 Area c1 20.11 79.89 Area a2 17.54 82.46 Area c2 18.77 81.23 Area a3 17.99 82.01 Area c3 20.91 79.09 Area a4 18.14 81.86 Area c4 19.12 80.88 Mean value 17.98 82.02 Mean value 19.73 80.27 Sample P300 (Fig. S5(b)) Sample T400 (Fig. S5(d)) Spot Co/% Sb/% Spot Co/% Sb/% Spot b1 15.69 84.31 Spot d1 19.87 80.13 Spot b2 19.65 80.35 Spot d2 19.19 80.81 Spot b3 14.22 85.78 Spot d3 19.76 80.24 Spot b4 17.23 82.77 Spot d4 19.82 80.18 Spot b5 18.87 81.13 Spot d5 21.77 78.23 Spot b6 21.34 78.66 Spot d6 22.09 77.91 Spot b7 18.58 81.42 Spot d7 21.68 78.32 Spot b8 16.64 83.36 Spot d8 18.56 81.44 Spot b9 20.75 79.25 Spot d9 18.58 81.42 Mean value 18.11 81.89 Mean value 20.15 79.85
Tools
Get Citation
Copy Citation Text
Lei YAO, Dongwang YANG, Yonggao YAN, Xinfeng TANG.
Paper Information
Category:
Received: Nov. 28, 2022
Accepted: --
Published Online: Dec. 28, 2023
The Author Email: YANG Dongwang (ydongwang@whut.edu.cn), TANG Xinfeng (tangxf@whut.edu.cn)
© Copyright 2018-2021 | Chinese Laser Press.
All Rights Reserved 沪ICP备15018463号-20