Journal of Inorganic Materials, Volume. 34, Issue 1, 96(2019)

Polymer PVP Additive for Improving Stability of Perovskite Solar Cells

Hao XIONG1... Bo-Xin ZHANG1, Wei JIA2, Qing-Hong ZHANG1, Hua-Qing XIE3, [in Chinese]1, [in Chinese]1, [in Chinese]2, [in Chinese]1 and [in Chinese]3 |Show fewer author(s)
Author Affiliations
  • 11. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  • 22. State Key Laboratory of Space Power Technology, Shanghai Institute of Power-Sources, Shanghai 200245, China
  • 33. College of Environmental and Materials Engineering, Shanghai Polytechnic University, Shanghai 201209, China
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    Figures & Tables(10)
    Surface SEM images of PbI2 films on the glass with or without polymer modification (a) Without PVP; (b) 0.2wt% PVP; (c) 0.4wt% PVP; (d) 0.6wt% PVP; (e) 0.8wt% PVP
    Surface SEM images of perovskite films with various concentration of PVP (a) Without PVP; (b) 0.2wt% PVP; (c) 0.4wt% PVP; (d) 0.6wt% PVP; (e) 0.8wt% PVP
    UV-visible absorption spectra of films in presence of varying concentration of PVP (a) PbI2 films; (b) CH3NH3PbI3 films
    Steady state photoluminescence (PL) spectra of perovskite films doped with various concentration of PVP on the glass
    XRD patterns of fresh perovskite films doped with PVP of various quantities; The optical photos from bottom to top in the inserted are 0, 0.2wt%, 0.4wt%, 0.6wt%, 0.8wt% PVP (PbI2 on the left, perovskite on the right)
    XRD patterns of CH3NH3PbI3 doped with PVP of various quantities after three weeks in the air; The optical photos from bottom to top in the inserted are 0, 0.2wt%, 0.4wt%, 0.6wt%, 0.8wt% PVP, respectively (PbI2 on the left, perovskite on the right)
    Photocurrent density-voltage (J-V) curves of the PSCs doped with various concentration of PVP
    • Table 1. The parameters of as-prepared perovskite solar cells doped with various concentration of PVP

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      Table 1. The parameters of as-prepared perovskite solar cells doped with various concentration of PVP

      SampleVoc/VJsc/(mA·cm-2)FF/%PCE/%
      Without PVP0.9516.1739.406.09
      0.2wt% PVP1.0019.1446.108.86
      0.4wt% PVP1.0419.6064.0013.07
      0.6wt% PVP1.0517.3967.7712.34
      0.8wt% PVP1.0414.8367.3810.42
    • Table 2. The parameters of perovskite solar cells doped with various concentration of PVP after three days in the air

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      Table 2. The parameters of perovskite solar cells doped with various concentration of PVP after three days in the air

      SampleVoc/VJsc/(mA·cm-2)FF/%PCE/%
      Without PVP1.0912.0531.644.17
      0.2wt% PVP0.7816.7548.366.33
      0.4wt% PVP1.0421.0553.0511.60
      0.6wt% PVP0.9921.4447.1210.02
      0.8wt% PVP0.8417.2066.109.52
    • Table 3. The parameters of perovskite solar cells doped with various concentration of PVP after three weeks in the air

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      Table 3. The parameters of perovskite solar cells doped with various concentration of PVP after three weeks in the air

      SampleVoc/VJsc/(mA·cm-2)FF/%PCE/%
      Without PVP0.956.1826.351.55
      0.2wt% PVP1.0315.5329.754.75
      0.4wt% PVP0.8015.1254.846.63
      0.6wt% PVP0.8210.8868.366.11
      0.8wt% PVP0.9721.1334.297.04
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    Hao XIONG, Bo-Xin ZHANG, Wei JIA, Qing-Hong ZHANG, Hua-Qing XIE, [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Polymer PVP Additive for Improving Stability of Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2019, 34(1): 96

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    Paper Information

    Category: Research Articles

    Received: Apr. 19, 2018

    Accepted: --

    Published Online: Feb. 4, 2021

    The Author Email:

    DOI:10.15541/jim20180172

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