Journal of Semiconductors, Volume. 45, Issue 2, 022501(2024)

Controllable step-flow growth of GaN on patterned freestanding substrate

Peng Wu1,2,3,4, Jianping Liu1、*, Lei Hu1, Xiaoyu Ren1, Aiqin Tian1, Wei Zhou1, Fan Zhang1,2, Xuan Li1, Masao Ikeda1, and Hui Yang1,2、**
Author Affiliations
  • 1Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China
  • 2School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
  • 3Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
  • 4University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(8)
    (Color online) Schematic top view of the patterns after processing, in which the trench width (g) is 20 μm, the stripe width (w) varies from 2 to 50 μm, the stripe length (l) is 210 μm and the height of the stripe is 0.5 μm, respectively.
    (Color online) Schematic diagram of the step-flow growth mode originated from sidewall on patterned substrate. The black steps denote miscut-induced steps while orange steps denote new steps from the sidewall.
    (Color online) 20 × 10 μm2 AFM amplitude images of sample A after 1st regrowth (a) and 2nd regrowth (b) and sample B after 1st regrowth (c) on the trench.
    18 × 9 μm2 AFM amplitude images of sample B after 2nd regrowth (a) and 3rd regrowth (c). (b) is 2 × 2 μm2 image close to m-plane sidewall in (a), (d) is 1 × 1 μm2 image close to m-plane sidewall in (c), respectively. The white dashed lines denote channels of about 1 nm deep.
    20 × 10 μm2 AFM amplitude images of sample C after 2nd regrowth (a) and 3rd regrowth (c). (b) and (d) are 2 × 2 μm2 image close to m-plane sidewall in (a) and (c), respectively. The white dashed lines denote channels of about 1 nm deep.
    (Color online) The sketch map of relations between the adatom density ns and terrace width ds of steps close to the m-plane sidewall. The red line denotes the condition of high temperature or large Ⅴ/Ⅲ ratio while black line denotes the condition of low temperature or small Ⅴ/Ⅲ ratio. nc is the critical adatom density for the occurrence of new steps from the sidewall, the terrace width is dc at the moment.
    (Color online) The simulated results of morphological change on the trench at a large dc (a) and a small dc (b). The black, red and blue lines denote the morphology at initial stage, after 1st regrowth and after 2nd regrowth, respectively. The steps above the grey dashed lines are new steps from the sidewall.
    • Table 1. The substrate information and growth conditions at different stages.

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      Table 1. The substrate information and growth conditions at different stages.

      SampleTMAH treatmentMiscut angle (º)k’th regrowthTemperature (°C)NH3 (mol/min)Ⅴ/Ⅲ ratioGrowth time (s)
      Aw/o0.419932591122150
      2300
      Bw/0.3319932591122150
      2940300
      3888150
      Cw/0.3419932591122150
      2223967150
      3188812150
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    Peng Wu, Jianping Liu, Lei Hu, Xiaoyu Ren, Aiqin Tian, Wei Zhou, Fan Zhang, Xuan Li, Masao Ikeda, Hui Yang. Controllable step-flow growth of GaN on patterned freestanding substrate[J]. Journal of Semiconductors, 2024, 45(2): 022501

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    Paper Information

    Category: Articles

    Received: Aug. 17, 2023

    Accepted: --

    Published Online: Apr. 24, 2024

    The Author Email: Liu Jianping (JPLiu), Yang Hui (HYang)

    DOI:10.1088/1674-4926/45/2/022501

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