Bulletin of the Chinese Ceramic Society, Volume. 44, Issue 6, 1988(2025)

Effect of Ethylenediamine Tetramethylene Phosphonic Acid on Early Hydration-Hardening of High Belite Calcium Sulfoaluminate Cement

TANG Ruifeng1,2, WANG Ziming2、*, CUI Suping2, ZHAO Sixue1, and RUI Yafeng1
Author Affiliations
  • 1Beijing Building Materials Academy of Sciences Research, Beijing 100041, China
  • 2College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
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    Aiming at the problem of fast setting time and poor workability of fast-setting and fast-hardening high belite calcium sulfoaluminate (HB-CSA) cement, the effect of ethylenediamine tetramethylene phosphonic acid (EDTMP) on the setting time, fluidity and mechanical properties of HB-CSA cement was investigated by hydration heat, X-ray diffraction, thermogravimetric and mercuric pressed tests. The mechanism of action of EDTMP in HB-CSA cement was analyzed. The results show that EDTMP can effectively retard the setting time of calcium sulfoaluminate cement and improve the fluidity. When the EDTMP contnet is 1.00% (mass fraction), it can prolong the initial setting time of HB-CSA cement to 62 min and prolong the final setting time of HB-CSA cement to 76 min. EDTMP can inhibit the reaction between anhydrous calcium sulfoaluminate (C4A3Sˉ) mineral and gypsum phase of HB-CSA cement in order to inhibit the rapid generation of ettringite (AFt), which is an early hydration product of cement, so that HB-CSA cement retarding can be achieved.

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    TANG Ruifeng, WANG Ziming, CUI Suping, ZHAO Sixue, RUI Yafeng. Effect of Ethylenediamine Tetramethylene Phosphonic Acid on Early Hydration-Hardening of High Belite Calcium Sulfoaluminate Cement[J]. Bulletin of the Chinese Ceramic Society, 2025, 44(6): 1988

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    Paper Information

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    Received: Jan. 15, 2025

    Accepted: Jul. 30, 2025

    Published Online: Jul. 30, 2025

    The Author Email: WANG Ziming (wangziming@bjut.edu.cn)

    DOI:10.16552/j.cnki.issn1001-1625.2024.1614

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