Chinese Journal of Quantum Electronics, Volume. 41, Issue 3, 506(2024)
Determination of nitrogen in water based on laser‐induced breakdown spectroscopy
Real-time, online, accurate, and rapid detection of eutrophic element nitrogen in water was achieved using aerosol assisted laser-induced breakdown spectroscopy (LIBS) in this work. In response to the limitation that the liquid lifting capacity of traditional concentric atomizer is affected by liquid physical characteristics, a micro-volume syringe pump is used in this work to achieve the same liquid lifting volume of samples with different salinity. As a result, the average relative standard deviation(DRSAV) of the absolute intensity of N I peak at 746.831 nm is reduced from 19.51% to 6.78%, the limit of detection (LoD) is improved from 5.45 mg/L to 1.57 mg/L, and the linear correction coefficient R2, average relative error (ER), and root mean square error of cross validation (ERMSCV) are improved from 0.2830, 45.80%, and 23.96 mg/L to 0.9043, 10.33%, and 4.28 mg/L, respectively. The results of this work indicate that the liquid aerosol assisted LIBS with the assistance of a micro injection pump for sample injection can be applied for accurate and sensitive detection of nitrogen in water.
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Xinyan YANG, Xin WANG, Dongdong LI, Xi WANG, Peng ZHU, Chang LIU, Xu ZHANG, Hongmei REN, Zhengbo QIN, Zefeng HUA, Xianfeng ZHENG. Determination of nitrogen in water based on laser‐induced breakdown spectroscopy[J]. Chinese Journal of Quantum Electronics, 2024, 41(3): 506
Category: Special Issue on Key Technologies and Applications of LIBS
Received: Nov. 10, 2023
Accepted: --
Published Online: Jul. 17, 2024
The Author Email: YANG Xinyan (xinyanyang@ahnu.edu.cn)