Chinese Journal of Quantum Electronics, Volume. 41, Issue 3, 506(2024)

Determination of nitrogen in water based on laser‐induced breakdown spectroscopy

YANG Xinyan1,2、*, WANG Xin1,2, LI Dongdong1,2, WANG Xi3, ZHU Peng1,2, LIU Chang1,2, ZHANG Xu1,2, REN Hongmei1,2, QIN Zhengbo1,2, HUA Zefeng1,2, and ZHENG Xianfeng1,2
Author Affiliations
  • 1School of Physics and Electronic Information, Anhui Normal University, Wuhu 241002, China
  • 2Anhui Province Key Laboratory for Control and Applications of Optoelectronic Information Materials, Wuhu 241002, China
  • 3Electronic Countermeasure Institute, National University of Defense Technology, Hefei 230037, China
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    Real-time, online, accurate, and rapid detection of eutrophic element nitrogen in water was achieved using aerosol assisted laser-induced breakdown spectroscopy (LIBS) in this work. In response to the limitation that the liquid lifting capacity of traditional concentric atomizer is affected by liquid physical characteristics, a micro-volume syringe pump is used in this work to achieve the same liquid lifting volume of samples with different salinity. As a result, the average relative standard deviation(DRSAV) of the absolute intensity of N I peak at 746.831 nm is reduced from 19.51% to 6.78%, the limit of detection (LoD) is improved from 5.45 mg/L to 1.57 mg/L, and the linear correction coefficient R2, average relative error (ER), and root mean square error of cross validation (ERMSCV) are improved from 0.2830, 45.80%, and 23.96 mg/L to 0.9043, 10.33%, and 4.28 mg/L, respectively. The results of this work indicate that the liquid aerosol assisted LIBS with the assistance of a micro injection pump for sample injection can be applied for accurate and sensitive detection of nitrogen in water.

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    Xinyan YANG, Xin WANG, Dongdong LI, Xi WANG, Peng ZHU, Chang LIU, Xu ZHANG, Hongmei REN, Zhengbo QIN, Zefeng HUA, Xianfeng ZHENG. Determination of nitrogen in water based on laser‐induced breakdown spectroscopy[J]. Chinese Journal of Quantum Electronics, 2024, 41(3): 506

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    Paper Information

    Category: Special Issue on Key Technologies and Applications of LIBS

    Received: Nov. 10, 2023

    Accepted: --

    Published Online: Jul. 17, 2024

    The Author Email: YANG Xinyan (xinyanyang@ahnu.edu.cn)

    DOI:10.3969/j.issn.1007-5461.2024.03.012

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