PhotoniX, Volume. 1, Issue 1, 17(2020)

Raman tensor of layered black phosphorus

Yanming Zhu... Wei Zheng*, Weiliang Wang, Siqi Zhu, Linxuan Li, Lu Cheng, Mingge Jin, Ying Ding and Feng Huang |Show fewer author(s)
Author Affiliations
  • State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials, Sun Yat-sen University, Guangzhou, 510275 Guangdong, China
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    Black phosphorus has a strong Raman anisotropy on the basal and cross planes due to its orthorhombic crystal structure. However, almost all the studies on black phosphorus’ anisotropy focus on basal plane with the cross plane neglected. Here, we performed a systematic angle-resolved polarized Raman scattering on both the basal and cross planes of black phosphorus and obtained its integral Raman tensors. It is discovered that when the polarization direction of excitation light is along different crystal axes, the Raman intensity ratio (Ixx : Iyy: Izz) of Ag1 mode is 256:1:5. Besides, via calculation, it is confirmed that the strong Raman anisotropy mainly comes from different differential polarizability alone different directions. This phenomenon is also observed when it comes to the Ag2 mode.

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    Yanming Zhu, Wei Zheng, Weiliang Wang, Siqi Zhu, Linxuan Li, Lu Cheng, Mingge Jin, Ying Ding, Feng Huang. Raman tensor of layered black phosphorus[J]. PhotoniX, 2020, 1(1): 17

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    Paper Information

    Category: Research Articles

    Received: Apr. 2, 2020

    Accepted: Jul. 6, 2020

    Published Online: Jul. 10, 2023

    The Author Email: Zheng Wei (zhengw37@mail.sysu.edu.cn)

    DOI:10.1186/s43074-020-00017-7

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