The hybrid sensitizer rhodamine B and coumarin or eosin and coumarin is used to sensitize nanocrystalline porous films. Absorption of the nanocrystalline photovoltaic cell (NPC) is improved in visible light. The performance of these cells is more effective than that of cells sensitized only by sensitizer rhodamine B or eosin. In the simulative solar light, cell sensitized by hybrid sensitizer rhodamine B and coumarin can get open circuit voltage (Voc) of 550 mV and short circuit current (Isc) of 0.1375 mA/cm2.