This study investigates the blasting demolition of a 180 m-high reinforced concrete chimney under site-specific conditions, systematically addressing critical challenges in collapse control through targeted engineering solutions. By designing symmetrically arranged directional and positioning windows, combined with empirical formula calculations, optimal blasting parameters were determined to be a 216 central angle and a 3.5 m cut height, effectively guiding the chimney's collapse along the predetermined trajectory without significant backward displacement. A 1:1 scale numerical model employing the Interface Stress Element Method was developed to simulate the collapse process, showing complete structural failure within 14.0 seconds with controlled lateral deviation (<0.5%) and minimal settlement/forward surge. A comparative analysis with the Decoupled Co-node Model revealed the superior performance of the Interface Stress Element Method in simulating rebar-concrete decoupling at cut closures, reducing backward displacement by approximately 1.0 m through differentiated load-bearing mechanisms at material component nodes. The model successfully replicated restrained rebar scattering during top section ground impact, due to the bonding forces of the spring elements, confirming enhanced simulation accuracy in collapse kinematics. Field implementation validated the numerical predictions, achieving precise directional collapse, complete structural disintegration, and compliance with safety thresholds, thereby establishing a replicable framework for ultra-high chimney demolition engineering.