A photonic crystal fiber(PCF) with zero dispersion wavelength around 800 nm is designed and fabricated. The simulated results show that the zero dispersion wavelength of fundamental mode of the PCF is at 825 nm and FMW is possible in fundamental mode. Anti-Stokes line around 610 nm can be generated efficiently with 810nm 200 fs Ti∶Sapphire laser used as pump. The output signal has a Gauss like field, which indicats that anti-Stokes signal is in the fundamental mode of PCF. The output energy of anti-Stokes signal is much more than the energy of residual pump laser. The maximum ratio of the anti-Stokes signal energy to the pump component in the output spectrum is estimated as 1.2 and the conversion efficiency is above 50%, wavelength conversion is achieved commendably.