Chinese Journal of Liquid Crystals and Displays, Volume. 38, Issue 8, 1005(2023)

Director distribution of nematic liquid crystals in a cylindrical cavity under electric field perpendicular to the cylindrical axis

Gui-jiao SUN, Yan-min LI, Yan-jun ZHANG*, Hui ZHANG, Zhi-guang LI, Gui-li ZHENG, and Ji-liang ZHU
Author Affiliations
  • School of Science, Hebei University of Technology, Tianjin 300401, China
  • show less

    The curved liquid-crystal system has different characteristics from the planar liquid-crystal system. In this paper, the director of nematic liquid crystal in a cylindrical cavity is studied by applying a uniform electric field perpendicular to the axis of the cylinder under the strong axial anchoring boundary condition. Based on the elastic continuum theory of liquid crystal, the equilibrium equations and boundary conditions of the system are given. The analytical solution of the threshold electric field for the deformation of the director is obtained. It is found that different elastic constants will lead to the asymmetry of the change of the director on the cross section of the cylindrical cavity. It provides a more accurate theoretical analysis for the experimental research of photonic crystal fibers.

    Keywords

    1 Introduction

    Nematic liquid crystals(NLCs)are anisotropic materials composed of rod-shaped molecules,and its optical anisotropy is determined by the orientation of rod-shaped liquid crystal(LC)molecules. It has been widely recognized that there are abundant physical phenomena in the finite and complex geometric structures. NLCs are often confined to some geometries,such as spherical droplets,capillary tubes and toroidal geometries1-5. The director of liquid crystals in a confined geometry is usually influenced by many factors,such as elastic anisotropy,surface anchoring,system size,external field effect,etc. Among the intricate geometries,the cylindrical cavity is considered to be the most intuitive geometry system6. A variety of alignment configurations of liquid crystals inside the cylindrical cavities are realized,which depends on different anchoring confidents and different elastic constants7-11.

    Liquid crystal is very sensitive to external field,which is used to control the orientation of liquid crystal molecules. The Fréedericskz transition in liquid crystals which is a second transition reflects a competition between elastic and electric or magnetic torques12. The transition has been studied not only in planar liquid crystal systems,but also in liquid crystal cylindrical systems. Nematic liquid crystals in the concentrical cylindrical cells under magnetic fields have been studied and the Fréedericskz transition has been analyzed by applying a radial magnetic field13 and a tangential magnetic field14-15. And the Fréedericskz transition in different initial states and anchoring conditions has been studied under electric fields in radial16-19 and axial electric fields19-20. In addition,nematic liquid crystals in a cylindrical cavity under axial electric field have been theoretically analyzed and it was found that the director can form an axial transition from an escaped radial configuration when the electric value exceeds the critical value21 and the flexoelectric effect affects the orientation of the director22.

    When the liquid crystal director changes,the optical23-25 and electrical properties of the device will change,which provides a promising Whispering gallery modes(WGMs)tuning scheme for the study of liquid crystal filled cylindrical microcavity26-27. Yang et al. designed an electrically tunable microresonator based on a grapefruit microstructured optical fiber(MOF)infiltrated with NLCs26. In the cross-sectional holes of the grapefruit MOF,the NLCs molecules turned out an escaped radial structure. When an electric field is applied in the direction perpendicular to the axis of the cylinder and with the enhancement of the applied electric field,the liquid crystal director gradually aligns along the direction of the electric field,and the WGMs resonance wavelength gradually shifts toward the shorter-wavelength region. Then Kong et al. designed an electrically tunable microresonator based on the Kagomé photonic crystal fibers infiltrated with NLCs which the initial state of liquid crystal director is along the cylindrical axis27. After the electric field is applied perpendicular to the cylindrical axis,the director of the liquid crystal gradually aligns along the direction of the electric field with the increase of the applied electric field. And the WGMs resonance wavelength gradually shifts toward the longer wavelength region. In both literatures,the experimental thresholds electric field have been obtained through the images of the change of WGM resonant wavelength with the applied electric field. When the electric field direction is perpendicular to the axis of the cylindrical cavity,as in the above experimental model,there is still no theoretical study of liquid crystal transition. In order to better understand and apply the LC director deformation in cylindrical cavity under external field,we will do further theoretical research based on the liquid crystal elastic theory.

    In this paper,the director distribution in nematic liquid crystals in cylindrical cavity under applied uniform electric field has been studied. Firstly,the geometric model of nematic liquid crystal in a cylindrical cavity under an electric field perpendicular to the cylindrical axis is described,and the equilibrium equation of the liquid crystal director is obtained by using the elastic theory. Then the expression of the threshold electric field under the one elastic constant approximation is derived by calculation. Finally,the director distribution of different liquid crystal materials in the cylindrical system is obtained by simulation.

    2 Model and Methods

    2.1 Establishment of theoretical model

    The orientation distribution of nematic liquid crystals filled with a cylindrical cavity under uniform electric field effects has been discussed. We assume the cylindrical radius is a and the cylindrical length is infinite. As shown in {L-End} Fig. 1(a),the initial state of the liquid crystals is that the director is oriented along the z-axis(cylindrical axis)and a uniform electric field was applied in the x-axis direction. The liquid crystal molecules with the positive dielectric anisotropy(∆ε>0)will turn to the direction of the electric field under the action of the electric field force. Therefore,it is reasonable to assume that the director changes in the x-z plane. As shown in {L-End} Fig. 1(b),the director n can be defined as

    n=sinθ,0,cosθ ,

    (a) Schematic diagram of the initial state of the cylindrical model;(b) Rectangular coordinate system for director.

    Figure 1.(a) Schematic diagram of the initial state of the cylindrical model;(b) Rectangular coordinate system for director.

    Where θ is the angle between the director and the z-axis.

    The electric field can be expressed as

    E=(E,0,0) .

    2.2 Derivation of equilibrium equation

    The equilibrium equation of nematic liquid crystal in cylindrical cavity according to the Frank theory was calculated18. The elastic free energy density is given by

    felast=12k11n2+12k22n×n2+12k33n××n2 .

    The dielectric free energy caused by electric field is

    felect=-12ε0ΔεEn2 .

    The total free energy density of liquid crystals confined in the cylinder is

    f=felast+felect=12k11cos2θ+k33sin2θdθdx2+12k22dθdy2-12ε0ΔεE2sin2θ2 .

    The total free energy per unit z-axis length is

    F=Dfdxdy

    where D is a circular region,which is the section perpendicular to the axis of the cylinder.

    For the convenience of studying the problem,the total free energy per unit z-axis length is transformed from rectangular coordinates into polar coordinates. There are some conversions,such as x=rcosφy=rsinφ and dxdy=rdrdφ. The free energy per unit z-axis length is converted to

    F=0a02πfrdrdφ .

    The equilibrium equation(8) can be obtained from the Euler-Lagrange equation.

    (k33-k11)sinθcosθsin2φθrθφ-rcos2φθr2-1rsin2φθφ2-k11cos2θ+k33sin2θsin2φθr+rcos2φ2θr2+1rsin2φθφ+1rsin2φ2θφ2-sin2φ2θrφ-k22rsin2φ2θr2+cos2φθr-1rsin2φθφ+1rcos2φ2θφ2+sin2φ2θrφ-rε0ΔεE2sinθcosθ=0 .

    The boundary conditions are

    θr=0=θm ,
    θr=a=0 ,

    where, θm is the maximum amplitude of θx).

    According to the equilibrium equation and the boundary conditions,the director distribution of nematic liquid crystal in the system can be calculated. The solutions of the equilibrium equation satisfying the above boundary are different with different elastic constants.

    3 Results and Discussion

    3.1 One elastic constant approximation

    In the following calculation,we solve the solution of the equation satisfying the boundary conditions in the one elastic constant approximation. The one elastic constant approximation satisfies k11=k22=k33=k.

    The equilibrium equation can be simplified to

    1rrrθr+1r22θφ2+ε0ΔεE2ksinθcosθ=0 .

    The voltage threshold of director deformation can be calculated. At the threshold point,the angle is small,i.e.,θ1. The equation can be transformed into

    1rrrθr+1r22θφ2+λ2θ=0 ,

    where λ2=ε0ΔεE2k.

    The general solution of the above equation is solved by a method of separating variables. If we take θ(r,φ)=R(r)Φ(φ) into Equation(12),we can obtain

    Φ(φ)+n2Φ(φ)=0 ,
    r2R(r)+rR'(r)+(λ2r2-n2)R(r)=0 .

    The solution of Equation(13) is Φn(φ)=Ancosnφ+Bnsinnφ. According to the boundary conditions,we can obtain that Ra)=0 and R(0)is a finite value. The solution of Equation(14) satisfying these boundary conditions is Bessel function Rr)=Jnλr28. If Ra)=0,λa=xmn,where xmn is the zero of the Bessel function Jnλr)and m represents the number of zeros.

    From the value of x10=2.404 8,we can obtain the electric threshold

    Ec=2.404 8akε0Δε .

    Equation(15) gives the threshold value of director deformation in the one elastic constant,which has the same order of magnitude as the experimental results. The electric field response threshold of nematic liquid crystal in the cylindrical cavity under the electric field perpendicular to the axis of the cylindrical cavity is given for the first time. It also provides theoretical support for the electro-tunable micro-resonator.

    Equations(8),(9)and(10)can also be solved by a finite-difference iterative method829. The liquid crystal parameters used to simulate the director distribution in the one elastic constant approximation are as follows:k11=k22=k33=k=5.85×10-12 N,∆ε=11.3 and a=0.5 μm. {L-End} Fig. 2 shows the numeri‑cal results of the simulation. As shown in {L-End} Fig. 2(a),in the case of the one elastic constant approximation,the electric threshold is about 1.16 V/μm,which is completely consistent with the result obtained by Equation(15). Further,we simulated the change of the director angle with position on the x-y plane under another electric field of 1.4 V/μm exceeding the threshold,as shown in {L-End} Fig. 2(b). Different colors represent different angles. The angle θ increases gradually from the edge to the center of the cylinder,and the angle at the center is the largest. It can also be seen intuitively that the deflection of the angle under the electric field is symmetrical in the x and y directions. In the x-y plane,the line with the same director angle presents a symmetrical circular change. We also calculated the curves of the director angle with x when y=0,and the curves of the director angle with y when x=0 under different electric fields,as shown in {L-End} Fig. 2(c). The electric field values are 1.1 V/μm,1.2 V/μm,1.3 V/μm,and 1.4 V/μm. Under the same electric field,the curves in x direction and y direction coincide. So the change of director in x direction and y direction is symmetrical. The liquid crystal in the cylindrical cavity has splay deformation and twist deformation under the electric field. Under the one elastic constant approximation,the splay coefficient and the twist coefficient are equal. The free energy of splay deformation is the same as that of twist deformation,and then the director shows a circular symmetry orientation change.

    Effect of electric field on director distribution of liquid crystal in cylindrical system under one elastic constant approximation. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.4 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields; (c) Curves of x1 and y1 coincide, curves of x2 and y2 coincide, curves of x3 and y3 coincide, and curves of x4 and y4 coincide.

    Figure 2.Effect of electric field on director distribution of liquid crystal in cylindrical system under one elastic constant approximation. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.4 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields; (c) Curves of x1 and y1 coincide, curves of x2 and y2 coincide, curves of x3 and y3 coincide, and curves of x4 and y4 coincide.

    3.2 Anisotropic elastic constants

    In order to better understand the change threshold and distribution of liquid crystal director,we further studied the director distribution of liquid crystal. The parameters of nematic liquid crystal 5CB(4-pentyl-4'-cyanobiphenyl)are as follows30 k11=5.85×10-12 N,k22/k11=0.6, k33=7.8×10-12 N,∆ε=11.3 and a=0.5 μm. It is difficult to obtain an electric threshold expression. The numerical results are obtained by the finite-difference iterative method in {L-End} Fig. 3.{L-End} Fig. 3(a)shows the change of the maximum angle with the electric field. It can be seen that the electric threshold is about 1.04 V/μm. {L-End} Fig. 3(b)shows the change of the director angle with position in the x-y plane in the electric field of 1.3 V/μm. We can see that the angle θ increases gradually from the edge to the center of the cylinder,and the angle θ is the largest at the center of the cylinder. The connecting line of the director angle of the cylindrical section is a slight non-circular asymmetric curve,which approximates a transverse ellipse. In order to further illustrate the symmetry of the change of director in the x-y plane,we calculate the curves of the director angle with x when y=0 and the curves of the director angle with y when x=0,in {L-End} Fig. 3(c). The values of electric field intensity are 1.0 V/μm,1.1 V/μm,1.2 V/μm and 1.3 V/μm. It can be seen that the curves of x1 and y1x2 and y2x3 and y3and x4 and y4 do not coincide perfectly. But the deviation between the two curves is very small. At the same distance from the center of the circle,the angle in the x-axis direction is greater than that in the y-axis direction. Therefore,it is known that the director has small asymmetry in the x direction and y direction. The splay coefficient of liquid crystal is greater than the twist coefficient,and then the free energy of the splay deformation of liquid crystal is greater than the free energy of the twist deformation. The difference between the coefficients of splay deformation and twist deformation leads to the asymmetric change.

    Effect of electric field on director distribution of liquid crystal 5CB in cylindrical system. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.3 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields.

    Figure 3.Effect of electric field on director distribution of liquid crystal 5CB in cylindrical system. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.3 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields.

    The elastic constants of some lyotropic liquid crystals are quite different from those of thermotropic liquid crystals,even one order of magnitude. For example,nematic lyotropic chromonic liquid crystal disodium cromoglycate(DSCG)has a relatively small k22,which is one order of magnitude smaller than k11. We take k11=5.85×10-12 N, k22/k11=0.05 for calculation. In order to compare the effect of elastic anisotropy,the above dielectric anisotropy parameter and cavity radius are still adopted. It can be seen from {L-End} Fig. 4(a)that the threshold voltage is about 0.80 V/μm. The liquid crystal elastic constant K22 is much smaller than K11,which is quite different from the above two cases. In {L-End} Fig. 4(b),the change of the angle with position in the x-y plane in another electric field of 1.1 V/μm exceeding the threshold was simulated. The angle θ increases gradually from the edge to the center of the cylinder,and the largest angle is at the center of the cylinder. There is an obvious non-circular asymmetric change in the connecting line of the director angle of the cylindrical section. It can be seen intuitively that the change ofangle θ with position is asymmetric. We also calculate the curves of the director angle with x when y=0 and the curves of the director angle with y when x=0 in four different electric fields of 0.6 V/μm,0.9 V/μm,1.0 V/μm and 1.1 V/μm,as shown in {L-End} Fig. 4(c). According to {L-End} Fig. 4(c),there is obvious asymmetry along x-axis and y-axis under a same electric field. At the same distance from the center of the circle,the angle in the x-axis direction is greater than that in the y-axis direction,which is more obvious than 5CB liquid crystal. The splay elastic constant is one order of magnitude larger than the twist elastic constant,resulting in obvious asymmetric change of the director.

    Effect of electric field on director distribution of liquid crystal with k22/k11=0.05 in cylindrical system. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.1 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields.

    Figure 4.Effect of electric field on director distribution of liquid crystal with k22/k11=0.05 in cylindrical system. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.1 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields.

    Further,we take k11=5.85×10-12 N, k22/k11=2 for simulation calculation. The dielectric anisotropy parameters and cavity radius are the same as above. It can be seen from {L-End} Fig. 5(a)that the thres‑hold voltage is about 1.40 V/μm. In {L-End} Fig. 5(b),the change of the angle with position in the x-y plane in another electric field of 1.8 V/μm exceeding the threshold was simulated. The largest angle is at the center of the cylinder and the angle θ increases gradually from the edge to the center of the cylinder. The change of θ with position in x-y plane is still asymmetric,but different from the previous case of k22<k11,the line with the same angle is similar to a vertical ellipse. We also calculate the curves of the director angle with x when y=0 and the curves of the director angle with y when x=0 in four different electric fields of 1.2 V/μm,1.6 V/μm,1.7 V/μm and 1.8 V/μm,as shown in {L-End} Fig. 5(c). It is still asymmetric along x-axis and y-axis under a same electric field. However,unlike the previous one,the angle in the y-axis direction is larger than that in the x-axis direction at the same distance from the center of the circle. The twist elastic constant is larger than the splay elastic constant resulting in the asymmetric change of the director.

    Effect of electric field on director distribution of liquid crystal k22/k11=2 in cylindrical system. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.8 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields.

    Figure 5.Effect of electric field on director distribution of liquid crystal k22/k11=2 in cylindrical system. (a) θm changed with the electric field; (b) θ changed with position in the x-y plane in the electric field of 1.8 V/μm; (c) Angle θ changed with the x-axis when y=0 and the angle θ changed with the y-axis when x=0 in the different electric fields.

    In our model,the director has only splay and twist deformation under the x-axis electric field. We assume that k in Equation(15) can be replaced by(k11+k22)/2 and the threshold formula can be

    Ec=2.4048ak112ε0Δε1+k22k11 .

    The change of the electric threshold with k22/k11 by Equation(16) is given,as shown in the black curve in {L-End} Fig. 6. The thresholds calculated by numerical simulation are also shown in {L-End} Fig. 6,which are represented by red dots. The ratios of the twist elastic constant and the splay elastic constant are k22/k11=1,k22/k11=0.6,k22/k11=0.05 and k22/k11=2,respectively. The threshold results are almost consistent. We also calculated the relationship between the threshold and the value of the bend elastic constant k33,and found that the thres‑hold is independent of the elastic constant k33. The above results prove the reliability of our hypothe‑tical equation.

    Threshold electric field changed with k22/k11 fields

    Figure 6.Threshold electric field changed with k22/k11 fields

    4 Conclusions

    In this work,we adopted the cylindrical cavity filled with nemaic liquid crystals to investigate the effect of external electric field on the distribution of liquid crystal director. When the electric field exceeds the electric field threshold and increases gradually,the liquid crystal director gradually turns towards the electric field. In the one elastic constant approximation,the threshold electric field expression has been obtained. The director changes symmetrically under the approximation of one constant. And the threshold electric field in the anisotropic elastic constants is approximately equal to the result of substituting k=(k11+k22)/2 into the above expression. It is found that the difference between the twist elastic constant k22 and the splay elastic constant k11 leads to the asymmetry of the variation of the director on the cross section of the cylindrical cavity. Our research has important guiding significance for studying on the orientation properties of the liquid crystals in the cylindrical cavity under the electric field and the design of the liquid crystal devices in the cylindrical cavity.

    [12] DE GENNES P G[M]. The Physics of Liquid Crystals(1974).

    [28] LIANG K M[M]. Mathematical Physical Method, 4(2010).

    Tools

    Get Citation

    Copy Citation Text

    Gui-jiao SUN, Yan-min LI, Yan-jun ZHANG, Hui ZHANG, Zhi-guang LI, Gui-li ZHENG, Ji-liang ZHU. Director distribution of nematic liquid crystals in a cylindrical cavity under electric field perpendicular to the cylindrical axis[J]. Chinese Journal of Liquid Crystals and Displays, 2023, 38(8): 1005

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: Research Articles

    Received: Feb. 22, 2023

    Accepted: --

    Published Online: Oct. 9, 2023

    The Author Email: Yan-jun ZHANG (zyj513@hebut.edu.cn)

    DOI:10.37188/CJLCD.2023-0070

    Topics