Bulletin of the Chinese Ceramic Society, Volume. 44, Issue 5, 1911(2025)

Synthesis and Luminescent Properties of Ba3Y1-x(BO3)3∶xTb3+ Phosphors

ZHOU Haijing1, SUN Jingwei2, CAO Yuxia1、*, and GUO Dongjie3
Author Affiliations
  • 1School of New Materials and Chemical Engineering, Tangshan University, Tangshan 063000, China
  • 2Tangshan Zhongkuo Testing Service Co., Ltd., Tangshan 063000, China
  • 3Tangshan Hexin Mould Manufacturing Co., Ltd., Tangshan 063000, China
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    In order to further improve the property of light emitting diode, the development of trichromatic phosphors is very crucial. In this paper, Ba3Y1-x(BO3)3∶xTb3+ phosphors were synthesized by high temperature solid state reaction method. The phase composition was analyzed by X-ray diffraction (XRD). In addition, the luminescent properties were studied by excitation-emission spectra, CIE 1931 chromatic coordinate and fluorescence lifetime. The results show that the crystalline structure of Ba3Y(BO3)3 is not changed obviously by doped by Tb3+, which indicate that Y3+ is replaced by Tb3+ in the crystal. The maximum peak of Ba3Y1-x(BO3)3∶xTb3+ phosphors locate at 543 nm after excited by a wavelength of 283 nm ultraviolet light. The luminescence intensity of the phosphors increases firstly and then decreases with the increase of Tb3+ doping concentration at 543 nm. The luminescence intensity of sample is the greatest when the Tb3+ doping concentration is 6% (mole fraction). Meanwhile, the energy transfer style between two Tb3+ is dipole-dipole interaction. After calculation, the colour purity of Ba3Y1-x(BO3)3∶xTb3+ (x=0.02, 0.04, 0.06, 0.08 and 0.10) phosphors are all more than 92% and their colour temperature are all in 5 000 to 6 000 K, which show that the Ba3Y1-x(BO3)3∶xTb3+ phosphors are green phosphors suitable for ultraviolet light excitation, and they may have potential applications in solid state lighting.

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    ZHOU Haijing, SUN Jingwei, CAO Yuxia, GUO Dongjie. Synthesis and Luminescent Properties of Ba3Y1-x(BO3)3∶xTb3+ Phosphors[J]. Bulletin of the Chinese Ceramic Society, 2025, 44(5): 1911

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    Paper Information

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    Received: Sep. 2, 2024

    Accepted: Jun. 12, 2025

    Published Online: Jun. 12, 2025

    The Author Email: CAO Yuxia (caoyuxia_416@126.com)

    DOI:10.16552/j.cnki.issn1001-1625.2024.1019

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