Time-resolved femtosecond coherent anti-Stokes Raman spectroscopy (fs-CARS) is utilized to measure the methane/oxygen/nitrogen flame temperature at atmospheric-pressure. The measurements are performed using the CARS signal of N2 with 40-fs laser pulses in the first few picoseconds after the initial in-phase excitation. Flame temperatures at 300 and 1 325 K are measured, the experimental results show good agreements with theoretical ones and present a good repeatability.