A method based on ferroelectric dipole to enhance surface charge density of triboelectric generator was proposed. By using the ferroelectric properties of polyvinylidene fluoride (PVDF), a positive charge trap was formed in the triboelectric layer to enhance the electric generating performance of the triboelectric material, so as to improve the surface charge density of the triboelectric nanogenerator. The PVDF film was fabricated by casting and uniaxial tensile process, and integrated into the triboelectric nanogenerator with vertical separation structure. The influences of the embedding direction, thickness and polarization intensity of the PVDF film on the output of the triboelectric nanogenerator were systematically studied. The results showed that the embedded PVDF piezoelectric film with a thickness of 100 μm and a maximum polarization electric field of 90 MV/m increased the peak power of the triboelectric nanogenerator by 2.6 times. This work has provided a new insight into regulating the properties of the triboelectric nanogenerator.