A reduced di-nuclear V^IV complex with the chemical formula ［V^IV₂O₃（L）（Me-Im）₄］ （1） was synthesized under solvothermal conditions， employing vanadium pentoxide （V₂O₅） as vanadium source， pyrazole-3，5-dicarboxylic acid （H₂L） and N-methylimidazole （Me-Im） as ligands. Complex 1 was fully characterized by single-crystal X-ray diffraction， powder X-ray diffraction， Fourier transform infrared spectroscopy， thermogravimetric analysis and X-ray photoelectron spectroscopy. The single-crystal X-ray diffraction results indicate that complex 1 crystallizes in the monoclinic system， with the space group P2₁/c. The structure contains two crystallographically independent V^IV ions， which are connected by the completely deprotonated pyrazole-3，5-dicarboxylic acid （L^2–） as a bridging ligand. Additionally， four Me-Im act as capping ligands， coordinating with these two V^IV ions， collectively constructing the zero-dimensional di-nuclear V^IV structure of complex 1. Furthermore， the magnetic properties of complex 1 were investigated due to the presence of single electrons in the V^IV d-orbital， and the results reveal the presence of ferromagnetic interactions in the compound.