Journal of Atmospheric and Environmental Optics, Volume. 20, Issue 1, 95(2025)

Development and preliminary application of portable hydrogen sulfide on-line detector

JIA Yanjie1, LI Rongguang2, SUN Ling2, SUN Dongyuan3, YU Licheng3, LI Lin4, TIAN Yali4, LI Chuanliang4, and QIU Xuanbing4,5、*
Author Affiliations
  • 1PipeChina Group Southwest Pipeline Co., LTD, Chengdu 610041, China
  • 2PipeChina Group North Pipeline Co., LTD, Langfang 065000, China
  • 3Hilong Group (Shanghai) Information Technology Limited Company, Shanghai 200949, China
  • 4Shanxi Province Engineering Research Center of Precision Measurement and Online Detection Equipment, School of Applied Science, Taiyuan University of Science and Technology, Taiyuan 030024, China
  • 5Shanxi Yangpu Photoelectric Technology Co., LTD, Yangquan 045008, China
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    Most of the natural gas mines in southwestern China are high-sulfur gas mines. Among high-sulfur gas, H2S presents a dual threat due to its high toxicity and propensity for corroding pipelines and instruments, which poses substantial safety hazards to gathering and transportation systems of natural gas. Therefore, rapid and precise monitoring of H2S level in natural gas is of great significance for improving the safety and efficiency of sulfur-laden natural gas production. In response to this demand, a portable H2S online detector based on tunable diode laser absorption spectroscopy (TDLAS) technology was developed in this work. The main body of the detector was a high-temperature long-path absorption cell with a base length of 15 cm, and it adopted a seven-ring spot scheme with an effective optical path of 30 m. In combination with a pulse width modulation controller and mass flowmeter controllers, a digital proportional controller was used to achieve constant pressure and temperature in the absorption cell. A near-infrared laser with a central wavelength of 1578 nm was used as the laser source of the detector, and based on complex programmable logic device and analog phase-locking technology, the second harmonic (2f) modulation and demodulation of H2S spectral signal were achieved. Furthermore, the hardware system and software program for the control end of the portable detector were developed, which enables real-time display, storage, and transmission of H2S concentration. The detector was calibrated using H2S standard gases, and the results showed that the linear correlation coefficient (R2) between the detected 2f spectral signal of H2S and H2S concentration is high to 0.99786. Finally, a field test of the developed instrument was conducted at a natural gas pigging station in southwestern China, and the test results showed that the H2S concentration in the natural gas pipeline was high, with a peak value of 1.16 mg/m3, and the pipeline corrosion was severe on site, which preliminarily demonstrated the applicability of the developed portable H2S online detector.

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    Yanjie JIA, Rongguang LI, Ling SUN, Dongyuan SUN, Licheng YU, Lin LI, Yali TIAN, Chuanliang LI, Xuanbing QIU. Development and preliminary application of portable hydrogen sulfide on-line detector[J]. Journal of Atmospheric and Environmental Optics, 2025, 20(1): 95

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    Paper Information

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    Received: Nov. 23, 2023

    Accepted: --

    Published Online: Feb. 21, 2025

    The Author Email: QIU Xuanbing (qiuxb@tyust.edu.cn)

    DOI:10.3969/j.issn.1673-6141.2025.01.008

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