Optical Instruments, Volume. 47, Issue 3, 51(2025)

Stability improvement of CsPbI3 perovskite quantum dots based on Pb-MOF

Xiaohua GAO and Gongjie XU*
Author Affiliations
  • School of Optical-Electrical and Computer Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
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    All-inorganic perovskite quantum dots CsPbI3 have excellent optical properties and are suitable for red light emitting diodes and solar cells. However, the large difference of their atomic radius, as well as the migration of halogen ion caused by the intrinsic soft-lattice nature, would lead to the phase transition and degradation of CsPbI3 quantum dots. In this paper, CsPbI3 quantum dots (CsPbI3@Pb-MOF-OLAMI) were synthesized using Pb metal organic framework (Pb-MOF) as lead sources in perovskite. The results showed that the thermal stability improves by 40%, and the light stability improves by 15 times after adding the lead iodide (PbI2) solution. This stability improvement is mainly due to the void-confinement effect. The porous structure of Pb-MOF hinders the migration of halogen ions, which avoids or reduces the formation of defects, and thus alleviates the degeneration of perovskite. This study provides a new strategy for improving the stability of CsPbI3 perovskite quantum dots.

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    Xiaohua GAO, Gongjie XU. Stability improvement of CsPbI3 perovskite quantum dots based on Pb-MOF[J]. Optical Instruments, 2025, 47(3): 51

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    Paper Information

    Received: Mar. 6, 2024

    Accepted: --

    Published Online: Jul. 28, 2025

    The Author Email: Gongjie XU (gjxu@usst.edu.cn)

    DOI:10.3969/j.issn.1005-5630.202403060036

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