Journal of Synthetic Crystals, Volume. 54, Issue 2, 177(2025)

Research Progress on p-Type Conduction of β Phase Gallium Oxide

ZHA Xianhu, WAN Yuxi*, and ZHANG Daohua
Author Affiliations
  • Shenzhen Pinghu Laboratory, Shenzhen 518111, China
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    β phase gallium oxide (β-Ga2O3) is an ideal semiconductor material for power devices based on its ultra-wide bandgap, high breakdown electric field, and easy preparation. However, it is still challenging to realize p-type doping of the β-Ga2O3 because of its relatively low energy of valence band maximum (VBM) and flat band dispersion near the VBM, which limits the development of p-n junctions and bipolar transistors. The main strategies for the p-type doping of β-Ga2O3 in recent research are based on size effect, defect regulation, non-equilibrium dynamic process, and solid solution. For the β-Ga2O3 p-n homojunction and heterojunction, improving crystal quality and reducing the interface defect states are the key issues for optimizing devices' performances. This paper focuses on the p-type conductivity problem of β-Ga2O3, systematically reviews the electronic structure of β-Ga2O3, the experimental characterization and theoretical calculation method of doping levels, the reasons for p-type doping difficulty, and the breakthrough in research advancements for improving the p-type doping of β-Ga2O3. Finally, the relevant studies on the β-Ga2O3 p-n homojunction and heterojunction devices are briefly reviewed. It requires further exploration to realize p-type doping of bulk-phase β-Ga2O3 through complex-defect regulation, non-equilibrium dynamics, solid solution, and combining these schemes. The device performances of p-n homojunction and heterojunction also need further optimization.

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    ZHA Xianhu, WAN Yuxi, ZHANG Daohua. Research Progress on p-Type Conduction of β Phase Gallium Oxide[J]. Journal of Synthetic Crystals, 2025, 54(2): 177

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    Paper Information

    Category:

    Received: Nov. 12, 2024

    Accepted: Mar. 31, 2025

    Published Online: Mar. 31, 2025

    The Author Email: WAN Yuxi (wanyuxi@phlab.com.cn)

    DOI:10.16553/j.cnki.issn1000-985x.2024.0285

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