Single crystals of near morphotropic phase boundary compositions in the family of Pb-containing tungsten bronze ferroelectric oxide (1-x)Pb2KNb5O15-xSr2NaNb5O15 (PSKNN) have been grown, for the first time, using the modified Laser Heated Pedestal Growth technique. The lead volatility has been controlled and compensated through adjusting the laser power and the Pb-enriched target composition. Both ［001］, ［100］ and ［110］ direction oriented single crystals can be grown by using properly chosen seed crystals. The ferroelectric, dielectric and piezoelectric properties of the grown single crystals are studied, and the morphotropic phase boundary composition in this solid solution family is discussed as well.