We demonstrate the theory of chromatic dispersion (CD)-induced constellation rotation (CR) in a radio-over-fiber (ROF) link and a method for compensation. We also propose a 60 GHz full-duplex ROF system with vector signal transmission including no CD effect. The evaluation of 5 Gb/s 16 quadrature amplitude modulation signal transmission shows that the CD-induced CR can be entirely overcome due to the proposed method which is simply implemented through an optical phase shifter. The proposed ROF schedule is not only applicable for V-band (57–64 GHz) but also fits for W-band (75–110 GHz), or any other bandwidth.