We calculate the 4p and 5s inner shell doubly excited Rydberg states of rubidium The spectral region is between 50 and 70 nm There is a little difference of the spectra with the different configurations Here, we report 4p6 5s 2S1/2→4p5 5s(3P2,1,,1P 1)ns,nd, the spectra of doubly excited Rydberg states from inner shell excitation and compare them with new experimental results[1].