TC4 titanium alloy was prepared by selective laser melting forming. The microstructure of TC4 titanium alloy in the as-deposited and heat-treated state was analyzed. The tensile strength and elongation of TC4 titanium alloy in heat treated state were tested by tensile test. The results show that the as-deposited titanium alloy has almost all non-equilibrium phase α' under rapid condensation and the structure is fine. When the solution heat treatment process is 960 ℃, 2 h, AC, the titanium alloy structure is converted from the non-equilibrium phase α' to the equilibrium phase α, the structure is coarsened into a strip shape, and the tensile strength of the sample can reach 1 056 MPa. The elongation rate reaches 16.9%, and the entire section has uniform and evenly distributed equiaxed dimples, which are typical ductile fractures. TC4 titanium alloy obtains better strength-plastic matching under heat treatment.