Chinese Journal of Lasers, Volume. 31, Issue 1, 97(2004)
Electrochemical Deposition and Stimulated Emission of Zinc Oxide Thin Films
Wide bandgap semiconductor zinc oxide thin films have been prepared by an electrochemical deposition performed in a chemical cell with three-electrodes, using an aqueous solution of Zn(NO_3)_2 as electrodeposition solution. The obtained ZnO thin films have optical bandgap of 3.35 eV and optical transmittance larger than 80% in the range of 400~2000 nm determined from their optical transmission spectra. XRD pattern indicates hexagonal wurtzite structure without c axis orientation for the ZnO thin films. AFM studies show a dense, irregular polycrystalline film structure with grain size below 250 nm. Stimulated emission occurs at a close ultraviolte wavelength of 403.9 nm under 355 nm optical pumping. When the excitation intensity exceeds a threshold (about 196.8 kW/cm2), very narrow emission peak (FWHM=0.5 nm) emerges and its intensity increases superlinearly with increasing the pump power. The stimulated eimission light is multimode laser relative to incident area and can be observed in all directions, showing a random laser emission due to the formation of a closed-loop path for scattered light in the ZnO thin film.
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[in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Electrochemical Deposition and Stimulated Emission of Zinc Oxide Thin Films[J]. Chinese Journal of Lasers, 2004, 31(1): 97