An asynchronous optical sampling scheme based on four-wave mixing (FWM) in highly nonlinear fiber (HNLF) is experimentally demonstrated. Based on this scheme, 10-GHz input pulse train with 1.8-ps pulse width is successfully sampled in 100-m HNLF. A single pulse at 10 GHz with 2.3-ps pulse width is rebuilt by using a 50-MHz frequency tunable free-running fiber laser as the sampling pulse source (SPS). 40-GHz pulse train is used as the input signal. The rebuilt waveforms, together with the low-jitter eye diagram, are also presented.