Semiconductor Optoelectronics, Volume. 46, Issue 2, 261(2025)

In Doping of Gallium Oxide Solar-Blind Deep-Ultraviolet Detector

LI Zhenqiu1, ZHONG Wansheng1, SHU Lincong2, LI Shan2, ZHANG Jiahan3, and LIU Zeng3
Author Affiliations
  • 1Hangzhou Xiaoshan Technician College, Hangzhou 311201, CHN
  • 2College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, CHN
  • 3School of Electronic Information Engineering, Inner Mongolia University, Hohhot 010021, CHN
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    Doping can significantly affect the optical absorption characteristics and electrical properties of Ga2O3 via bandgap modulation, thus improving the performance of photodetectors. This study uses plasma-enhanced chemical vapor deposition (PECVD) to fabricate In-doped Ga2O3 films and investigates the influence mechanism and application potential of In doping on the performance of β-Ga2O3-based solar-blind photodetectors. This photodetector demonstrates remarkable deep-ultraviolet (DUV) response properties, reaching a photocurrent level of microamperes under 5 V bias and 275 μW/cm2 illumination at a wavelength of 254 nm. Additionally, it achieves a maximum responsivity of 480 mA/W, a detectivity of 6.42×1013 Jones, an external quantum efficiency of 235%, a photoconductive gain of 2.15, and a maximum photo-to-dark current ratio of approximately 1×106, thus demonstrating the extremely high sensitivity of In-doped Ga2O3 to low DUV light intensities and establishing its significant potential in optical sensing applications. High-temperature growth facilitates In doping; therefore, the photocurrent of In-doped β-Ga2O3 films is significantly higher than that of their counterparts without In doping under identical illumination and bias conditions. The presence of oxygen vacancies and lattice defects in the films significantly affects the performance of the photodetector, with surface oxygen vacancies affecting electron accumulation and migration through the adsorption of oxygen molecules and the formation of surface barriers. Consequently, the photocurrent response is enhanced under 254 nm ultraviolet light, whereas the optical-response parameters diminish as the light intensity increases, which is primarily due to the scattering and recombination of charge carriers. This study provides a comprehensive discussion on the fabrication methods and photoelectronic characteristics of In-doped Ga2O3 films. Our findings offer new insights into the design of high-efficiency In-doped Ga2O3 DUV photodetectors and provide new avenues for the application of PECVD technology in semiconductor materials.

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    LI Zhenqiu, ZHONG Wansheng, SHU Lincong, LI Shan, ZHANG Jiahan, LIU Zeng. In Doping of Gallium Oxide Solar-Blind Deep-Ultraviolet Detector[J]. Semiconductor Optoelectronics, 2025, 46(2): 261

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    Paper Information

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    Received: Nov. 13, 2024

    Accepted: Sep. 18, 2025

    Published Online: Sep. 18, 2025

    The Author Email:

    DOI:10.16818/j.issn1001-5868.20241113002

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