Journal of Advanced Dielectrics, Volume. 15, Issue 4, 2540012(2025)

Mössbauer study of cation substitution effect on magnetic phase transitions in (1x)BiFeO3xAFe0.5B0.5O3(A=Ba, Sr, Pb; B=Nb, Sb) solid solutions

S. P. Kubrin, I. V. Lisnevskaya, I. G. Sheptun, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, V. V. Titov, S. I. Raevskaya*, A. V. Motseyko, N. V. Ter-Oganessian, E. A. Erofeeva, and I. P. Raevski

Ceramic samples of (1x)BiFeO3xPbFe0.5Sb0.5O3(BFO–xPFS), (1x)BiFeO3xSrFe0.5Sb0.5O3(BFO–xSFS) where (x=0.05,0.1,,0.9), (1x)BiFeO3xBaFe0.5Nb0.5O3 (BFO–xBFN) and (1x)BiFeO3xSrFe0.5Nb0.5O3 (BFO–xSFN) where (x=0,0.01,0.02,,0.1,0.2,,1) solid solutions with a perovskite structure were obtained. Mössbauer studies have shown that the Neel temperature TN concentration dependences of the systems studied are in good agreement with TN(x) calculated under the assumption of the ordered distribution of Fe3+ and nonmagnetic Sb5+ ions in the lattice. The TN values obtained for BFO–xBFN and BFO–xPFS are close to the values, calculated for cases of the disordered and ordered distribution of Fe3+ and nonmagnetic Nb5+ and Sb5+ ions in the lattice, respectively. The TN values of BFO–xSFN and BFO–xSFS are in the range between the calculated values for ordered and disordered cases. Moreover the anomaly on the TN(x) dependence for the BFO–xBFN and BFO–xSFN systems was found near x=0.7. This anomaly is most likely related to the destruction of the magnetic super exchange via the empty 6p state of Bi3+ ions.

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S. P. Kubrin, I. V. Lisnevskaya, I. G. Sheptun, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, V. V. Titov, S. I. Raevskaya, A. V. Motseyko, N. V. Ter-Oganessian, E. A. Erofeeva, I. P. Raevski. Mössbauer study of cation substitution effect on magnetic phase transitions in (1x)BiFeO3xAFe0.5B0.5O3(A=Ba, Sr, Pb; B=Nb, Sb) solid solutions[J]. Journal of Advanced Dielectrics, 2025, 15(4): 2540012

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Paper Information

Category: Research Articles

Received: Nov. 15, 2024

Accepted: Apr. 14, 2025

Published Online: Aug. 5, 2025

The Author Email: S. I. Raevskaya (siraevskaya@sfedu.ru)

DOI:10.1142/S2010135X25400120

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