Journal of Advanced Dielectrics, Volume. 15, Issue 4, 2540012(2025)
Mössbauer study of cation substitution effect on magnetic phase transitions in ()BiFeOAFeBO3(ABa, Sr, Pb; BNb, Sb) solid solutions
S. P. Kubrin, I. V. Lisnevskaya, I. G. Sheptun, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, V. V. Titov, S. I. Raevskaya*, A. V. Motseyko, N. V. Ter-Oganessian, E. A. Erofeeva, and I. P. Raevski
Ceramic samples of ()BiFeOPbFeSbO3(BFO–xPFS), ()BiFeOSrFeSbO3(BFO–xSFS) where (), ()BiFeOBaFeNbO3 (BFO–xBFN) and ()BiFeOSrFeNbO3 (BFO–xSFN) where () solid solutions with a perovskite structure were obtained. Mössbauer studies have shown that the Neel temperature concentration dependences of the systems studied are in good agreement with calculated under the assumption of the ordered distribution of Fe and nonmagnetic Sb ions in the lattice. The values obtained for BFO–xBFN and BFO–xPFS are close to the values, calculated for cases of the disordered and ordered distribution of Fe and nonmagnetic Nb and Sb ions in the lattice, respectively. The values of BFO–xSFN and BFO–xSFS are in the range between the calculated values for ordered and disordered cases. Moreover the anomaly on the dependence for the BFO–xBFN and BFO–xSFN systems was found near . This anomaly is most likely related to the destruction of the magnetic super exchange via the empty 6p state of Bi ions.
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S. P. Kubrin, I. V. Lisnevskaya, I. G. Sheptun, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, V. V. Titov, S. I. Raevskaya, A. V. Motseyko, N. V. Ter-Oganessian, E. A. Erofeeva, I. P. Raevski. Mössbauer study of cation substitution effect on magnetic phase transitions in ()BiFeOAFeBO3(ABa, Sr, Pb; BNb, Sb) solid solutions[J]. Journal of Advanced Dielectrics, 2025, 15(4): 2540012
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