Acta Photonica Sinica, Volume. 54, Issue 5, 0530001(2025)
Photoacoustic SO2 Sensor for Detecting SF6 Decomposition Product in High-pressure Gas Insulation Equipment
Gas-insulation equipment is a key equipment for urban power grids and high-voltage power transmission. The chemical properties of SF6 gas are usually very stable, but when latent faults such as discharge or overheating occur inside the equipment, SF6 will decompose to produce toxic and corrosive gases such as SO2. SO2 indicates whether there is an arc or spark discharge fault in the equipment, and the SO2 content produced is closely related to the severity of the internal defects of the equipment. Electrochemical sensing, semiconductor sensing and gas chromatography are the main traditional methods for detecting SF6 decomposition products. However, they generally have disadvantages such as low sensitivity, large cross-interference, short life or long response time. Photoacoustic spectroscopy uses the sensed absorption energy to achieve gas detection and is a background-free and highly selective trace gas detection solution. SO2 gas has absorption in both mid-infrared and ultraviolet bands, ultraviolet Light-Emitting Diode (LED) has the characteristics of low cost, simple structure, low power consumption and good stability. Using photoacoustic spectroscopy and low-cost ultraviolet LED excitation source, a photoacoustic SO2 sensor with high sensitivity, high reliability and miniaturization for SF6 decomposition product in high-pressure gas insulation equipment is designed and implemented. An integrated photoacoustic SO2 sensor was designed, which mainly includes an excitation source, a lens group, a photoacoustic cell, a Micro-Electro-Mechanical System (MEMS) microphone, a gas pressure sensor, a window, an air inlet valve, an air outlet valve, an inlet and an outlet. The photoacoustic cell is a device for holding the gas to be measured, and the photoacoustic effect is generated here. The reasonable design of the photoacoustic cell structure is conducive to the improvement of the photoacoustic signal and the signal-to-noise ratio. The cell constant of the photoacoustic cell working in the non-resonance mode is inversely proportional to the square of the radius of the photoacoustic tube and the modulation frequency of the incident excitation light. The gas chamber volume and dimensions of the sensor are only 10.2 mL and 40 mm×40 mm×36 mm. This miniaturized design makes the sensor have the advantages of low gas consumption, simple structure and portability. Photoacoustic gas sensors are affected by gas pressure. The gas pressure range in the gas chamber of gas-insulation equipment is approximately 0.25~0.4 MPa. The photoacoustic signal is related to the degree of collision between the gas molecules to be measured. Theoretically, when the gas to be measured is in a state of non-saturated absorption and the gas concentration and the incident excitation power are constant, the high gas pressure will increase the energy absorbed by the gas molecules to be measured, thereby stimulating a stronger photoacoustic signal. Theoretical analysis and simulation verified the promoting effect of high pressure on photoacoustic excitation under SF6 background gas. The integrated pressure sensor is used to display the gas pressure value in real-time, and the influence of gas pressure on the photoacoustic response, background signal, noise and detection limit is tested. Real-time monitoring of SO2 concentration generated by SF6 decomposition to achieve accurate analysis and early warning of latent fault types and severity within gas-insulation equipment. Taking advantage of the positive correlation between photoacoustic excitation and gas pressure, the high sensitivity of the photoacoustic SO2 sensor in a high pressure environment is achieved. The performance of the photoacoustic SO2 sensor is tested under a gas pressure environment of 0.4 MPa. Detection limit is one of the most important factors in evaluating a sensing system. The results show that the detection limit reaches 56 ppb with an averaging time is 100 s, which provides a powerful preventive measure for the safe and stable operation of high-pressure gas insulation equipment.
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Fengxiang MA, Chen HANG, Xinyu ZHAO, Yajie ZHANG, Hongchao QI, Yue ZHAO, Feng ZHU, Ke CHEN. Photoacoustic SO2 Sensor for Detecting SF6 Decomposition Product in High-pressure Gas Insulation Equipment[J]. Acta Photonica Sinica, 2025, 54(5): 0530001
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Received: Nov. 7, 2024
Accepted: Jan. 17, 2025
Published Online: Jun. 18, 2025
The Author Email: Ke CHEN (chenke@dlut.edu.cn)