A method of measuring thermal diffusivity of materials at room temperature by photothermal reflection technique is described. An intensity-modulated Ar+ laser beam is used as incident light. The beam is focused to about 1 mm diameter spot and illuminates the sample surface. HgCdTe infrared detector is used to receive photothermal signal. Using this technique, the photothermal signals are experimentally measured as the function of different frequencies. The thermal diffusivities can be obtained by fitting the experimental data. On the other hand, the thermal diffusivities of one-way composite and orthogonalsymmetric arranged composites Al2O3/Al are measured in transverse, longitudinal and arbitrary directions. The results show that the diffusivity of one-way material decreases with the increase of the measurement angle; the diffusivity of orthogonally arranged material almost keeps the same when measurement angle changes.