Journal of Radiation Research and Radiation Processing, Volume. 42, Issue 4, 040204(2024)

Radiation preparation of nano-oxide@microcrystalline cellulose and its adsorption and removal of trichloroacetic acid

Lili FU1,2,3, Zhijun WANG1,3, Kun LIU1,2,3, Dongxu TANG1,3, Jinyu YANG3, Huangqin CHEN2、*, and Yuesheng LI3,4、**
Author Affiliations
  • 1School of Pharmacy, Hubei University of Science and Technology, Xianning 437100, China
  • 2School of Stomatology and Optometry, Hubei University of Science and Technology, Xianning 437100, China
  • 3Hubei Key Labortory of Radiation Chemistry and Functional Materials,Hubei University of Science and Technology, Xianning 437100, China
  • 4Hubei Industrial Technology Research Institute of Intelligent Health, Hubei University of Science and Technology, Xianning 437100, China
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    Trichloroacetic acid is a common nonvolatile byproduct of drinking water disinfection and poses carcinogenic risks to the human body. In this study, four types of nano-oxide@microcrystalline-cellulose-based adsorbents (P25@microcrystalline cellulose, SiO?@microcrystalline cellulose (MCC-g-GMA@SiO2), Fe3O4@microcrystalline cellulose, and Fe2O3@microcrystalline cellulose) were successfully prepared by the pre-radiation grafting-embedding method. Subsequently, their ability to remove trichloroacetic acid from drinking water was investigated. The micro zonation morphology and surface properties of the materials were characterized and tested using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), Thermogravimetric (TG) analysis, and Scanning electron microscopy (SEM) characterization methods. The effects of monomer concentration, embedding concentration, and absorbed dose on the weight gain rate were systematically investigated. A complete static adsorption equilibrium curve was obtained on the basis of the results of adsorption experiments of four buried nano-oxides. The performance of SiO2@microcrystalline cellulose was found to be significantly higher than that of the other three adsorbents. When the volum percentage of monomer concentration was 30%, the mass percentage of embedding concentration was 4%, and the absorbed dose was 60 kGy, the removal rate of trichloroacetic acid in drinking water reached 83.27%. This series of adsorbent materials present significant potential for practical application in drinking water purification.

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    Lili FU, Zhijun WANG, Kun LIU, Dongxu TANG, Jinyu YANG, Huangqin CHEN, Yuesheng LI. Radiation preparation of nano-oxide@microcrystalline cellulose and its adsorption and removal of trichloroacetic acid[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(4): 040204

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    Paper Information

    Category: RADIATION CHEMISTRY

    Received: Oct. 15, 2023

    Accepted: Jan. 14, 2024

    Published Online: Sep. 14, 2024

    The Author Email: CHEN Huangqin (陈黄琴), LI Yuesheng (李月生)

    DOI:10.11889/j.1000-3436.2023-0089

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