Journal of Inorganic Materials, Volume. 34, Issue 8, 803(2019)

Attapulgite/g-C3N4 Composites: Synthesis and Electrocatalytic Oxygen Evolution Property

Sheng ZHANG... Yi JIANG, Yuan-Yuan JI, Ying DU, Zhen-Huan SHENG, Jing-Zhou YIN, Qiao-Qi LI and Li-Li ZHANG* |Show fewer author(s)
Author Affiliations
  • Jiangsu Environmental Engineering Laboratory, Jiangsu Key Laboratory for Low-dimension Materials, School of Chemistry and Chemical Enginering, Huaiyin Normal University, Huaian 223300, China
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    Figures & Tables(12)
    XRD patterns of different catalysts (a) and ATP/g-C3N4 with different proportions (b)
    Infrared spectra of (a) different catalysts (a) and ATP/g-C3N4 with different proportions (b)
    XPS spectra of ATP/g-C3N4-0.5 samples
    SEM images of g-C3N4(a) and ATP(b), SEM image (c) and (d) EDAX pattern of ATP/ g-C3N4-0.50
    TG (a) and DSC (b) curves of different samples
    Cyclic voltammograms of catalytic materials
    (a) LSV of ATP/g-C3N4-w and mechanical mixture, (b) LSV of g-C3N4 and ATP/g-C3N4, (c) LSV and the over potential (d) of ATP/g-C3N4-w
    Tafel curves of g-C3N4 and ATP/g-C3N4-w
    EIS curves of the oxygen evolution anode material
    I-t curve of constant potential electrolysis of ATP/g-C3N4-0.50
    • Table 1. Specific surface area of each sample

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      Table 1. Specific surface area of each sample

      SampleSBET/(m2•g-1)
      ATP190.800
      g-C3N48.821
      ATP/g-C3N4-0.3326.980
      ATP/g-C3N4-0.4038.280
      ATP/g-C3N4-0.5053.180
      ATP/g-C3N4-0.6782.440
    • Table 2. Oxygen evolution overpotential E(V vs RHE) and overpotential of the catalyst at 10 mA/cm2 and the slope of the Tafel curve

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      Table 2. Oxygen evolution overpotential E(V vs RHE) and overpotential of the catalyst at 10 mA/cm2 and the slope of the Tafel curve

      SampleE/V(vs RHE)η/mVTafel slope/(mV•dec-1)
      g-C3N41.73500155
      ATP/g-C3N4-0.671.68450175
      ATP/g-C3N4-0.501.64410118
      ATP/g-C3N4-0.401.65420128
      ATP/g-C3N4-0.331.69460143
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    Sheng ZHANG, Yi JIANG, Yuan-Yuan JI, Ying DU, Zhen-Huan SHENG, Jing-Zhou YIN, Qiao-Qi LI, Li-Li ZHANG. Attapulgite/g-C3N4 Composites: Synthesis and Electrocatalytic Oxygen Evolution Property[J]. Journal of Inorganic Materials, 2019, 34(8): 803

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    Paper Information

    Category: RESEARCH PAPER

    Received: Aug. 15, 2018

    Accepted: --

    Published Online: Sep. 26, 2021

    The Author Email: ZHANG Li-Li (zll@hytc.edu.cn)

    DOI:10.15541/jim20180373

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