Journal of Inorganic Materials, Volume. 38, Issue 11, 1364(2023)

Characterization of High Temperature Resistivity and Full Matrix Material Coefficient of LGT Crystals

Maoxin SU1...2, Xinchen LI1, Kainan XIONG2, Sheng WANG2, Yunlin CHEN1,*, Xiaoniu TU2,* and Erwei SHI2 |Show fewer author(s)
Author Affiliations
  • 11. Institute of Applied Micro-Nano Materials, School of Science, Beijing Jiaotong University, Beijing 100049, China
  • 22. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
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    Figures & Tables(9)
    Pictures of LGT and LGAT crystals
    High temperature resistivities of LGT and LGAT crystals in different atmospheres
    Ultrasonic resonance spectra of LGT crystal at 20 and 400 ℃
    Measured and calculated resonant frequencies at 20 and 400 ℃
    • Table 1. Activation energy of LGT and LGAT crystal in different atmospheres

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      Table 1. Activation energy of LGT and LGAT crystal in different atmospheres

      AtmosphereT /℃ Ea(LGT)/eV Ea(LGAT)/eV
      Oxygen400-5001.140.99
      525-6501.05
      Nitrogen400-5501.00.95
      550-7001.361.26
      Argon400-7000.840.91
    • Table 2. Clamping dielectric constant of LGT crystal

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      Table 2. Clamping dielectric constant of LGT crystal

      T/℃ $\varepsilon _{11}^{\text{S}}/{{\varepsilon }_{0}}$$\varepsilon _{33}^{\text{S}}/{{\varepsilon }_{0}}$
      2018.675.9
      40019.859.7
    • Table 3. Inversion results of LGT crystal elasticity and piezoelectric coefficient

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      Table 3. Inversion results of LGT crystal elasticity and piezoelectric coefficient

      T/℃Elastic coefficient/(×1010, N·m-2) Piezoelectric coefficient/(C·m-2)
      $c_{11}^{\text{E}}$$c_{12}^{\text{E}}$$\text{ }\!\!~\!\!\text{ }c_{13}^{\text{E}}$$c_{14}^{\text{E}}$$c_{33}^{\text{E}}$$c_{44}^{\text{E}}$${{e}_{11}}$${{e}_{14}}$
      2018.58610.5249.7851.35326.0035.093-0.4390.123
      40018.34610.3149.6941.25625.3405.056-0.4290.209
    • Table 4. Full matrix material coefficient of LGT crystal at 20 ℃

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      Table 4. Full matrix material coefficient of LGT crystal at 20 ℃

      $c_{ij}^{\text{E}}$/(×1010, N·m–2) $c_{ij}^{\text{D}}$/(×1010, N·m–2)
      $c_{11}^{\text{E}}$$c_{12}^{\text{E}}$$c_{13}^{\text{E}}$$c_{14}^{\text{E}}$$c_{33}^{\text{E}}$$c_{44}^{\text{E}}$$c_{11}^{\text{D}}$$c_{12}^{\text{D}}$$c_{\text{13}}^{\text{D}}$$c_{\text{14}}^{\text{D}}$$c_{\text{33}}^{\text{D}}$$c_{\text{44}}^{\text{D}}$
      18.58610.5249.7851.35326.0035.09318.70310.4069.7851.32026.0035.102
      $s_{ij}^{\text{E}}$/(×10–12, m2·N–1)$s_{ij}^{\text{D}}$/(×10–12, m2·N–1)
      $s_{\text{11}}^{\text{E}}$$s_{\text{12}}^{\text{E}}$$s_{\text{13}}^{\text{E}}$$s_{\text{14}}^{\text{E}}$$s_{\text{33}}^{\text{E}}$$s_{\text{44}}^{\text{E}}$$s_{\text{11}}^{\text{D}}$$s_{\text{12}}^{\text{D}}$$s_{\text{13}}^{\text{D}}$$s_{\text{14}}^{\text{D}}$$s_{\text{33}}^{\text{D}}$$s_{\text{44}}^{\text{D}}$
      9.108-4.509-1.731-3.6175.14821.568.866-4.268-1.731-3.3975.14821.36
      ${{e}_{ij}}$/(C·m–2)${{d}_{ij}}$/(×10–12, C·N–1)
      ${{e}_{11}}$${{e}_{14}}$${{d}_{11}}$${{d}_{14}}$
      -0.4390.123-6.435.83
      ${{g}_{ij}}$/(×10–2, ${{\text{V}}_{m}}$·N–1)${{h}_{ij}}$/(×108, V·m–1)
      ${{g}_{11}}$${{g}_{14}}$${{h}_{11}}$${{h}_{14}}$
      -3.9033.543-26.677.482
      $\varepsilon _{ij}^{\text{T}}$ (ε0)$\varepsilon _{ij}^{\text{S}}$ (ε0)$\beta _{ij}^{\text{T}}$ (×10–4 /ε0)$\beta _{ij}^{\text{S}}$(×10–4/ε0)
      $\varepsilon _{\text{11}}^{\text{T}}$$\varepsilon _{\text{33}}^{\text{T}}$$\varepsilon _{\text{11}}^{\text{S}}$$\varepsilon _{\text{33}}^{\text{S}}$$\beta \ _{\text{11}}^{\text{T}}$$\beta _{\text{33}}^{\text{T}}$$\beta \ _{\text{11}}^{\text{S}}$$\beta _{\text{33}}^{\text{S}}$
      19.375.918.675.9518132538132
    • Table 5. Full matrix material coefficient of LGT crystal at 400 ℃

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      Table 5. Full matrix material coefficient of LGT crystal at 400 ℃

      $c_{ij}^{\text{E}}$/(×1010, N·m–2) $c_{ij}^{\text{D}}$/(×1010, N·m–2)
      $c_{\text{11}}^{\text{E}}$$c_{\text{12}}^{\text{E}}$$c_{\text{13}}^{\text{E}}$$c_{\text{14}}^{\text{E}}$$c_{\text{33}}^{\text{E}}$$c_{\text{44}}^{\text{E}}$$c_{\text{11}}^{\text{D}}$$c_{\text{12}}^{\text{D}}$$c_{\text{13}}^{\text{D}}$$c_{\text{14}}^{\text{D}}$$c_{\text{33}}^{\text{D}}$$c_{\text{44}}^{\text{D}}$
      18.34610.3149.6941.25625.3405.05618.45110.2099.6941.20525.3405.081
      $s_{ij}^{\text{E}}$/(×10-12, m2·N–1)$s_{ij}^{\text{D}}$/(×10-12, m2·N–1)
      $s_{\text{11}}^{\text{E}}$$s_{\text{12}}^{\text{E}}$$s_{\text{13}}^{\text{E}}$$s_{\text{14}}^{\text{E}}$$s_{\text{33}}^{\text{E}}$$s_{\text{44}}^{\text{E}}$$s_{\text{11}}^{\text{D}}$$s_{\text{12}}^{\text{D}}$$s_{\text{13}}^{\text{D}}$$s_{\text{14}}^{\text{D}}$$s_{\text{33}}^{\text{D}}$$s_{\text{44}}^{\text{D}}$
      9.103-4.396-1.801-3.3535.32421.448.873-4.165-1.801-3.0925.32421.15
      ${{e}_{ij}}$/(C·m–2)${{d}_{ij}}$/(×10–12, C·N–1)
      e11e14d11d14
      -0.4290.209-6.487.34
      ${{g}_{ij}}$/(×10–2, ${{\text{V}}_{m}}$·N–1)${{h}_{ij}}$/(×108, V·m–1)
      g11g14h11h14
      -3.6994.190-24.4511.89
      $\varepsilon _{ij}^{\text{T}}$ (ε0)$\varepsilon _{ij}^{\text{S}}$ (ε0)$\beta _{ij}^{\text{T}}$ (×10–4/ε0)$\beta _{ij}^{\text{S}}$ (×10–4/ε0)
      $\varepsilon _{11}^{\text{T}}$$\varepsilon _{33}^{\text{T}}$$\varepsilon _{11}^{\text{S}}$$\varepsilon _{33}^{\text{S}}$$\beta _{11}^{\text{T}}$$\beta _{33}^{\text{T}}$$\beta \ _{11}^{\text{S}}$$\beta _{33}^{\text{S}}$
      20.659.719.859.7485168505168
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    Maoxin SU, Xinchen LI, Kainan XIONG, Sheng WANG, Yunlin CHEN, Xiaoniu TU, Erwei SHI. Characterization of High Temperature Resistivity and Full Matrix Material Coefficient of LGT Crystals[J]. Journal of Inorganic Materials, 2023, 38(11): 1364

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    Paper Information

    Category:

    Received: Feb. 28, 2023

    Accepted: --

    Published Online: Mar. 6, 2024

    The Author Email: CHEN Yunlin (ylchen@bjtu.edu.cn), TU Xiaoniu (xiaoniu_tu@mail.sic.ac.cn)

    DOI:10.15541/jim20230101

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