Journal of Inorganic Materials, Volume. 39, Issue 4, 449(2024)

Effect of Pb2+ on the Luminescent Performance of Borosilicate Glass Coated CsPbBr3 Perovskite Quantum Dots

Zihao YUE1...2, Xiaotu YANG1, Zhengliang ZHANG1, Ruixiang DENG1,*, Tao ZHANG1,*, and Lixin SONG12 |Show fewer author(s)
Author Affiliations
  • 11. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
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    Figures & Tables(8)
    Schematic of preparation of quantum dots glass- ceramicsAC: After crystallization; BC: Before crystallization
    Crystal structures and optical properties of PQDs@glass at different temperatures for 2 h(a) XRD patterns; (b) PL spectra; (c) PLQY and PL intensity; (d) Fluorescence lifetime curvesColorful images are available on website
    TEM characterization and size distribution analyses of PQDs@glass(a, b) TEM images before (a) and after (b) heat-treatment; (c) High-resolution TEM image; (d, e) TEM image and EDS mappings; (f) Schematic diagram of the relationship between size and band gap of CsPbBr3 QDs; (g-k) TEM images and size statistics
    (a) Photographs, (b) XRD patterns and (c) PL spectra of CsPbBr3 QDs@glass with different Pb2+ concentrations
    Structural characterization of PQDs@glass at different Pb2+ concentrations(a, b) FT-IR and XPS spectra, and (c) the ratio of bridging to non-bridging oxygen bonds; Colorful figures are available on website
    Stability experiments of PQDs@glass(a, b) Variations in PL intensity and FWHM of water resistance (a) and UV stability (b), and (c) experimental results of thermal cycling stability
    (a) LED device fabricated with CsPbBr3 QDs@glass, and (b) CIE coordinates of CsPbBr3 QDs@glass LED devices at different Pb2+ concentrations
    • Table 1.

      Component regulation of Pb2+ ions (all data in molar ratios)

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      Table 1.

      Component regulation of Pb2+ ions (all data in molar ratios)

      CodeSiO2H3BO3ZnOCaF2Cs2CO3PbBr2NaBrPbO
      Pb-185170555164170.5
      Pb-285170555165150.5
      Pb-385170555166130.5
      Pb-485170555167110.5
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    Zihao YUE, Xiaotu YANG, Zhengliang ZHANG, Ruixiang DENG, Tao ZHANG, Lixin SONG. Effect of Pb2+ on the Luminescent Performance of Borosilicate Glass Coated CsPbBr3 Perovskite Quantum Dots [J]. Journal of Inorganic Materials, 2024, 39(4): 449

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    Paper Information

    Category:

    Received: Oct. 30, 2023

    Accepted: --

    Published Online: Jul. 8, 2024

    The Author Email: DENG Ruixiang (dengruixiang@mail.sic.ac.cn), ZHANG Tao (tzhang@mail.sic.ac.cn)

    DOI:10.15541/jim230501

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