Laser & Optoelectronics Progress, Volume. 57, Issue 23, 233002(2020)

LIBS-Based Element Detection and Quality Identification of Huanglongbing Navel Oranges

Zhang Linying1,2, Li Jing1,2, Rao HongHui1,2, Zhou HuaMao1,2, Huang Lin2,3, Liu MuHua1,2, Chen JinYin3, and Yao MingYin1,2、*
Author Affiliations
  • 1College of Engineering, Jiangxi Agricultural University, Nanchang, Jiangxi 330045, China
  • 2Jiangxi Key Laboratory of Modern Agricultural Equipment, Nanchang, Jiangxi 330045, China
  • 3Collaborative Innovation Center of Postharvest Key Technology and Quality Safety of Fruits and Vegetables in Jiangxi Province, Nanchang, Jiangxi 330045, China
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    Figures & Tables(7)
    Schematic of element detection using LIBS
    LIBS images of Huanglongbing and healthy navel orange juices
    Original LIBS image and 9SM+MSC spectrum of Huanglongbing navel orange juices
    Scatter plot of Huanglongbing and healthy navel orange juices
    • Table 1. Differences in true concentration of healthy and Huanglongbing navel oranges

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      Table 1. Differences in true concentration of healthy and Huanglongbing navel oranges

      ParameterHuanglongbing navel orangeHealthy navel orangeT valuep value
      Mass fraction of Ca/(μg·g-1)595.1±153.5415.6±75.1-2.9520.016
      Mass fraction of K/(μg·g-1)669.6±146.5575.3±50.8-1.9140.088
      Mass fraction of Zn/(μg·g-1)47.0±15.232.2±11.92.7200.017
      Sugar content /°Brix8.7±1.811.4±1.46.4070
    • Table 2. Differences in LIBS characteristic spectral intensity of healthy and Huanglongbing navel orange juices

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      Table 2. Differences in LIBS characteristic spectral intensity of healthy and Huanglongbing navel orange juices

      ParameterHuanglongbing navel orangeHealthy navel orangeT valuep value
      Intensity of Ca II 393.37 nm5577.9±1435.84997.3±965.01.8500.082
      Intensity of Ca II 396.68 nm3641.3±945.23136.0±591.62.5330.021
      Intensity of Ca I 422.67 nm453.2±95.2609.7±150.6-4.8770
      Intensity of Mg II 279.55 nm1152.2±168.51226.5±158.1-1.3260.202
      Intensity of Mg I 794.44 nm1009.9±107.71258.5±98.4-9.7250
      Intensity of Mg II 821.39 nm3255.3±391.74413.9±355.4-14.6200
      Intensity of Mg I 844.57 nm3242.3±107.74117.2±98.4-11.1570
      Intensity of K I 766.49 nm5357.4±861.85144.9±881.51.5020.152
      Intensity of Na I 588.99 nm1112.5±201.82747.6±1028.9-7.5870
      Intensity of Fe II 769.63 nm4930.6±417.55778.4±430.6-6.2720
      Intensity of Fe II 867.85 nm3797±442.95004.1±361.9-13.6860
      Intensity of C I 247.86 nm358.3±52.5467.0±73.1-9.0390
      Intensity of H I 656.28 nm9219.8±1595.810500.5±1961.0-10.0380
      Intensity of O I 777.19 nm12672.0±2218.315004.5±1552.1-4.4710
    • Table 3. Identification accuracies of healthy and Huanglongbing navel oranges using different models

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      Table 3. Identification accuracies of healthy and Huanglongbing navel oranges using different models

      Test setParameterPCA-MLPPCA-RBF
      Healthy navel orangeHuanglongbingnavel orangeHealthy navel orangeHuanglongbingnavel orange
      Training setCorrect number123114109124
      Error number881810
      Precision rate /%93.893.485.892.5
      Forecast setCorrect number46554844
      Error number3355
      Precision rate /%93.994.890.695.7
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    Zhang Linying, Li Jing, Rao HongHui, Zhou HuaMao, Huang Lin, Liu MuHua, Chen JinYin, Yao MingYin. LIBS-Based Element Detection and Quality Identification of Huanglongbing Navel Oranges[J]. Laser & Optoelectronics Progress, 2020, 57(23): 233002

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    Paper Information

    Category: Spectroscopy

    Received: Mar. 9, 2020

    Accepted: --

    Published Online: Nov. 30, 2020

    The Author Email: MingYin Yao (mingyin800@126.com)

    DOI:10.3788/LOP57.233002

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