Moderate Fields, Maximum Potential: Achieving High Records with Temperature-Stable Energy Storage in Lead-Free BNT-Based Ceramics

Wenjing Shi; Leiyang Zhang; Ruiyi Jing; Yunyao Huang; Fukang Chen; Vladimir Shur; Xiaoyong Wei; Gang Liu; Hongliang Du; Li Jin

doi:10.1007/s40820-023-01290-4

Nano-Micro Letters, Volume. 16, Issue 1, 091(2024)

Moderate Fields, Maximum Potential: Achieving High Records with Temperature-Stable Energy Storage in Lead-Free BNT-Based Ceramics

Wenjing Shi¹, Leiyang Zhang¹, Ruiyi Jing¹, Yunyao Huang¹, Fukang Chen², Vladimir Shur³, Xiaoyong Wei¹, Gang Liu^2、*, Hongliang Du^4、**, and Li Jin^1、***

Author Affiliations

¹Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, School of Electronic Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China

²School of Materials and Energy, Southwest University, Chongqing 400715, People’s Republic of China

³School of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg 620000, Russia

⁴Multifunctional Electronic Ceramics Laboratory, College of Engineering, Xi’an International University, Xi’an 710077, People’s Republic of China

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References(84)

[1] [1] Z. Yao, Z. Song, H. Hao, Z. Yu, M. Cao et al., Homogeneous/inhomogeneous-structured dielectrics and their energy-storage performances. Adv. Mater. 29, 1601727 (2017). 10.1002/adma.201601727

[2] [2] J. Li, F. Li, Z. Xu, S. Zhang, Multilayer lead-free ceramic capacitors with ultrahigh energy density and efficiency. Adv. Mater. 30, 1802155 (2018). 10.1002/adma.201802155

[3] [3] J. Li, Z. Shen, X. Chen, S. Yang, W. Zhou et al., Grain-orientation-engineered multilayer ceramic capacitors for energy storage applications. Nat. Mater. 19, 999–1005 (2020). 10.1038/s41563-020-0704-x

[4] [4] L. Yang, X. Kong, F. Li, H. Hao, Z. Cheng et al., Perovskite lead-free dielectrics for energy storage applications. Prog. Mater. Sci. 102, 72–108 (2019). 10.1016/j.pmatsci.2018.12.005

[5] [5] G. Wang, Z. Lu, Y. Li, L. Li, H. Ji et al., Electroceramics for high-energy density capacitors: current status and future perspectives. Chem. Rev. 121, 6124–6172 (2021). 10.1021/acs.chemrev.0c01264

[6] [6] Z. Yang, H. Du, L. Jin, D. Poelman, High-performance lead-free bulk ceramics for electrical energy storage applications: design strategies and challenges. J. Mater. Chem. A 9, 18026–18085 (2021). 10.1039/D1TA04504K

[7] [7] G. Liu, Y. Li, B. Guo, M. Tang, Q. Li et al., Ultrahigh dielectric breakdown strength and excellent energy storage performance in lead-free Barium titanate-based relaxor ferroelectric ceramics via a combined strategy of composition modification, viscous polymer processing, and liquid-phase sintering. Chem. Eng. J. 398, 125625 (2020). 10.1016/j.cej.2020.125625

[8] [8] L. Zhang, R. Jing, Y. Huang, Q. Hu, D.O. Alikin et al., Enhanced antiferroelectric-like relaxor ferroelectric characteristic boosting energy storage performance of (Bi0.5Na0.5)TiO3-based ceramics via defect engineering. J. Materiomics 8, 527–536 (2022). 10.1016/j.jmat.2022.01.007

[9] [9] L. Jin, F. Li, S. Zhang, Decoding the fingerprint of ferroelectric loops: comprehension of the material properties and structures. J. Am. Ceram. Soc. 97, 1–27 (2014). 10.1111/jace.12773

[10] [10] H.Y. Zhou, X.Q. Liu, X.L. Zhu, X.M. Chen, CaTiO3 linear dielectric ceramics with greatly enhanced dielectric strength and energy storage density. J. Am. Ceram. Soc. 101, 1999–2008 (2018). 10.1111/jace.15371

[11] [11] H. Wang, Y. Liu, T. Yang, S. Zhang, Ultrahigh energy-storage density in antiferroelectric ceramics with field-induced multiphase transitions. Adv. Funct. Mater. 29, 1807321 (2019). 10.1002/adfm.201807321

[12] [12] J. Lv, Q. Li, Y. Li, M. Tang, D. Jin et al., Significantly improved energy storage performance of NBT-BT based ceramics through domain control and preparation optimization. Chem. Eng. J. 420, 129900 (2021). 10.1016/j.cej.2021.129900

[13] [13] L. Zhang, M. Zhao, Y. Yang, Y. Li, M. Tang et al., Achieving ultrahigh energy density and ultrahigh efficiency simultaneously via characteristic regulation of polar nanoregions. Chem. Eng. J. 465, 142862 (2023). 10.1016/j.cej.2023.142862

[14] [14] H. Palneedi, M. Peddigari, G.-T. Hwang, D.-Y. Jeong, J. Ryu, High-performance dielectric ceramic films for energy storage capacitors: progress and outlook. Adv. Funct. Mater. 28, 1803665 (2018). 10.1002/adfm.201803665

[15] [15] L. Chen, H. Yu, J. Wu, S. Deng, H. Liu et al., Large energy capacitive high-entropy lead-free ferroelectrics. Nano-Micro Lett. 15, 65 (2023). 10.1007/s40820-023-01036-2

[16] [16] J. Shi, Y. Zhao, J. He, T. Li, F. Zhu et al., Deferred polarization saturation boosting superior energy-storage efficiency and density simultaneously under moderate electric field in relaxor ferroelectrics. ACS Appl. Energy Mater. 5, 3436–3446 (2022). 10.1021/acsaem.1c04017

[17] [17] J. Zhao, T. Hu, Z. Fu, Z. Pan, L. Tang et al., Delayed polarization saturation induced superior energy storage capability of BiFeO3-based ceramics via introduction of non-isovalent ions. Small 19, e2206840 (2023). 10.1002/smll.202206840

[18] [18] W. Wang, L. Zhang, R. Jing, Q. Hu, D.O. Alikin et al., Enhancement of energy storage performance in lead-free Barium titanate-based relaxor ferroelectrics through a synergistic two-step strategy design. Chem. Eng. J. 434, 134678 (2022). 10.1016/j.cej.2022.134678

[19] [19] W. Wang, L. Zhang, C. Li, D.O. Alikin, V.Y. Shur et al., Effective strategy to improve energy storage properties in lead-free (Ba0.8Sr0.2)TiO3-Bi(Mg0.5Zr0.5)O3 relaxor ferroelectric ceramics. Chem. Eng. J. 446, 137389 (2022). 10.1016/j.cej.2022.137389

[20] [20] X. Ren, L. Jin, Z. Peng, B. Chen, X. Qiao et al., Regulation of energy density and efficiency in transparent ceramics by grain refinement. Chem. Eng. J. 390, 124566 (2020). 10.1016/j.cej.2020.124566

[21] [21] Z. Yang, F. Gao, H. Du, L. Jin, L. Yan et al., Grain size engineered lead-free ceramics with both large energy storage density and ultrahigh mechanical properties. Nano Energy 58, 768–777 (2019). 10.1016/j.nanoen.2019.02.003

[22] [22] G. Liu, Y. Li, M. Shi, L. Yu, P. Chen et al., An investigation of the dielectric energy storage performance of Bi(Mg2/3Nb1/3)O3-modifed BaTiO3 Pb-free bulk ceramics with improved temperature/frequency stability. Ceram. Int. 45, 19189–19196 (2019). 10.1016/j.ceramint.2019.06.166

[23] [23] G. Liu, Y. Li, J. Gao, D. Li, L. Yu et al., Structure evolution, ferroelectric properties, and energy storage performance of CaSnO3 modified BaTiO3-based Pb-free ceramics. J. Alloys Compd. 826, 154160 (2020). 10.1016/j.jallcom.2020.154160

[24] [24] T. Wang, L. Zhang, A. Zhang, J. Liu, L. Kong et al., Synergistic enhanced energy storage performance of NBT-KBT ceramics by K0.5Na0.5NbO3 composition design. J. Alloys Compd. 948, 169725 (2023). 10.1016/j.jallcom.2023.169725

[25] [25] B. Guo, Y. Yan, M. Tang, Z. Wang, Y. Li et al., Energy storage performance of Na0.5Bi0.5TiO3 based lead-free ferroelectric ceramics prepared via non-uniform phase structure modification and rolling process. Chem. Eng. J. 420, 130475 (2021). 10.1016/j.cej.2021.130475

[26] [26] G. Liu, Y. Wang, G. Han, J. Gao, L. Yu et al., Enhanced electrical properties and energy storage performances of NBT-ST Pb-free ceramics through glass modification. J. Alloys Compd. 836, 154961 (2020). 10.1016/j.jallcom.2020.154961

[27] [27] L. Zhang, S. Cao, Y. Li, R. Jing, Q. Hu et al., Achieving ultrahigh energy storage performance over a broad temperature range in (Bi0.5Na0.5)TiO3-based eco-friendly relaxor ferroelectric ceramics via multiple engineering processes. J. Alloys Compd. 896, 163139 (2022). 10.1016/j.jallcom.2021.163139

[28] [28] G. Liu, J. Dong, L. Zhang, Y. Yan, R. Jing et al., Phase evolution in (1–x)(Na0.5Bi0.5)TiO3−xSrTiO3 solid solutions: a study focusing on dielectric and ferroelectric characteristics. J. Materiomics 6, 677–691 (2020). 10.1016/j.jmat.2020.05.005

[29] [29] S. Wu, B. Fu, J. Zhang, H. Du, Q. Zong et al., Superb energy storage capability for NaNbO3-based ceramics featuring labyrinthine submicro-domains with clustered lattice distortions. Small 19, e2303915 (2023). 10.1002/smll.202303915

[30] [30] H. Wang, S. Wu, B. Fu, J. Zhang, H. Du et al., Hierarchically polar structures induced superb energy storage properties for relaxor Bi0.5Na0.5TiO3-based ceramics. Chem. Eng. J. 471, 144446 (2023). 10.1016/j.cej.2023.144446

[31] [31] T. Karthik, S. Asthana, Enhanced mechanical and ferroelectric properties through grain size refinement in site specific substituted lead free Na0.5–xK x Bi0.5 TiO3 (x = 0–0.10) ceramics. Mater. Lett. 190, 273–275 (2017). 10.1016/j.matlet.2017.01.025

[32] [32] R. Jing, L. Zhang, Q. Hu, D.O. Alikin, V.Y. Shur et al., Phase evolution and relaxor to ferroelectric phase transition boosting ultrahigh electrostrains in (1–x)(Bi1/2Na1/2)TiO3-x(Bi1/2K1/2)TiO3 solid solutions. J. Materiomics 8, 335–346 (2022). 10.1016/j.jmat.2021.09.002

[33] [33] C. Wang, X. Yang, Z. Wang, C. He, X. Long, Investigation of switching behavior of acceptor-doped ferroelectric ceramics. Acta Mater. 170, 100–108 (2019). 10.1016/j.actamat.2019.03.033

[34] [34] T. Kainz, M. Naderer, D. Schütz, O. Fruhwirth, F.A. Mautner et al., Solid state synthesis and sintering of solid solutions of BNT–xBKT. J. Eur. Ceram. Soc. 34, 3685–3697 (2014). 10.1016/j.jeurceramsoc.2014.04.040

[35] [35] Y. Liu, Y. Li, Z. Zheng, W. Kang, K. Xi et al., Dielectric temperature stability of Nb-modified Bi0.5(Na0.78K0.22)0.5TiO3 lead-free ceramics. Ceram. Int. 47, 4933–4936 (2021). 10.1016/j.ceramint.2020.10.067

[36] [36] R.D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. Sect. A 32, 751–767 (1976). 10.1107/s0567739476001551

[37] [37] T. Wang, L. Jin, C. Li, Q. Hu, X. Wei, Relaxor ferroelectric BaTiO3–Bi(Mg2/3Nb1/3)O3 ceramics for energy storage application. J. Am. Ceram. Soc. 98, 559–566 (2015). 10.1111/jace.13325

[38] [38] C. Sun, X. Chen, J. Shi, F. Pang, X. Dong et al., Simultaneously with large energy density and high efficiency achieved in NaNbO3-based relaxor ferroelectric ceramics. J. Eur. Ceram. Soc. 41, 1891–1903 (2021). 10.1016/j.jeurceramsoc.2020.10.049

[39] [39] L. Jin, W. Luo, L. Wang, Y. Tian, Q. Hu et al., High thermal stability of electric field-induced strain in (1–x)(Bi0.5Na0.5)TiO3-xBa0.85Ca0.15Ti0.9Zr0.1O3 lead-free ferroelectrics. J. Eur. Ceram. Soc. 39, 277–286 (2019). 10.1016/j.jeurceramsoc.2018.09.019

[40] [40] W. Jo, S. Schaab, E. Sapper, L.A. Schmitt, H.-J. Kleebe et al., On the phase identity and its thermal evolution of lead free (Bi1/2Na1/2)TiO3-6 mol% BaTiO3. J. Appl. Phys. 110, 074106 (2011). 10.1063/1.3645054

[41] [41] Y. Hiruma, Y. Imai, Y. Watanabe, H. Nagata, T. Takenaka, Large electrostrain near the phase transition temperature of (Bi0.5Na0.5)TiO3–SrTiO3 ferroelectric ceramics. Appl. Phys. Lett. 92, 262904 (2008). 10.1063/1.2955533

[42] [42] H. Zhang, P. Xu, E. Patterson, J. Zang, S. Jiang et al., Preparation and enhanced electrical properties of grain-oriented (Bi1/2Na1/2)TiO3-based lead-free incipient piezoceramics. J. Eur. Ceram. Soc. 35, 2501–2512 (2015). 10.1016/j.jeurceramsoc.2015.03.012

[43] [43] J. Zang, W. Jo, H. Zhang, J. Rödel, Bi1/2Na1/2TiO3–BaTiO3 based thick-film capacitors for high-temperature applications. J. Eur. Ceram. Soc. 34, 37–43 (2014). 10.1016/j.jeurceramsoc.2013.07.020

[44] [44] G. Viola, H. Ning, X. Wei, M. Deluca, A. Adomkevicius et al., Dielectric relaxation, lattice dynamics and polarization mechanisms in Bi0.5Na0.5TiO3-based lead-free ceramics. J. Appl. Phys. 114, 014107 (2013). 10.1063/1.4812383

[45] [45] A.A. Bokov, Z.-G. Ye, Recent progress in relaxor ferroelectrics with perovskite structure. J. Mater. Sci. 41, 31–52 (2006). 10.1007/s10853-005-5915-7

[46] [46] V.V. Shvartsman, D.C. Lupascu, Lead-free relaxor ferroelectrics. J. Am. Ceram. Soc. 95, 1–26 (2012). 10.1111/j.1551-2916.2011.04952.x

[47] [47] T. Wang, J. Hu, H. Yang, L. Jin, X. Wei et al., Dielectric relaxation and Maxwell-Wagner interface polarization in Nb2O5 doped 06.5BiFeO3–0.35BaTiO3 ceramics. J. Appl. Phys. 121, 084103 (2017). 10.1063/1.4977107

[48] [48] L.E. Cross, Relaxor ferroelectrics. Ferroelectrics 76, 241–267 (1987). 10.1080/00150198708016945

[49] [49] H. Pan, S. Lan, S. Xu, Q. Zhang, H. Yao et al., Ultrahigh energy storage in superparaelectric relaxor ferroelectrics. Science 374, 100–104 (2021). 10.1126/science.abi7687

[50] [50] H. Pan, F. Li, Y. Liu, Q. Zhang, M. Wang et al., Ultrahigh-energy density lead-free dielectric films via polymorphic nanodomain design. Science 365, 578–582 (2019). 10.1126/science.aaw8109

[51] [51] C. Zhu, Z. Cai, B. Luo, L. Guo, L. Li et al., High temperature lead-free BNT-based ceramics with stable energy storage and dielectric properties. J. Mater. Chem. A 8, 683–692 (2020). 10.1039/c9ta10347c

[52] [52] L. Zhang, R. Jing, Y. Huang, Q. Hu, D.O. Alikin et al., Ultrahigh electrostrictive effect in potassium sodium niobate-based lead-free ceramics. J. Eur. Ceram. Soc. 42, 944–953 (2022). 10.1016/j.jeurceramsoc.2021.11.037

[53] [53] W. Wang, L. Zhang, W. Shi, Y. Yang, D. Alikin et al., Enhanced energy storage properties in lead-free (Na0.5Bi0.5)0.7Sr0.3TiO3-based relaxor ferroelectric ceramics through a cooperative optimization strategy. ACS Appl. Mater. Interfaces 15, 6990–7001 (2023). 10.1021/acsami.2c21969

[54] [54] W. Wang, L. Zhang, Y. Yang, W. Shi, Y. Huang et al., Enhancing energy storage performance in Na0.5Bi0.5TiO3-based lead-free relaxor ferroelectric ceramics along a stepwise optimization route. J. Mater. Chem. A 11, 2641–2651 (2023). 10.1039/D2TA09395B

[55] [55] W. Jo, T. Granzow, E. Aulbach, J. Rödel, D. Damjanovic, Origin of the large strain response in (K0.5Na0.5)NbO3-modified (Bi0.5Na0.5)TiO3–BaTiO3 lead-free piezoceramics. J. Appl. Phys. 105, 094102 (2009). 10.1063/1.3121203

[56] [56] G. Viola, Y. Tian, C. Yu, Y. Tan, V. Koval et al., Electric field-induced transformations in bismuth sodium titanate-based materials. Prog. Mater. Sci. 122, 100837 (2021). 10.1016/j.pmatsci.2021.100837

[57] [57] W. Shi, L. Zhang, R. Jing, Q. Hu, X. Zeng et al., Relaxor antiferroelectric-like characteristic boosting enhanced energy storage performance in eco-friendly (Bi0.5Na0.5)TiO3-based ceramics. J. Eur. Ceram. Soc. 42, 4528–4538 (2022). 10.1016/j.jeurceramsoc.2022.04.057

[58] [58] N. Luo, K. Han, M.J. Cabral, X. Liao, S. Zhang et al., Constructing phase boundary in AgNbO3 antiferroelectrics: pathway simultaneously achieving high energy density and efficiency. Nat. Commun. 11, 4824 (2020). 10.1038/s41467-020-18665-5

[59] [59] A. Xie, R. Zuo, Z. Qiao, Z. Fu, T. Hu et al., NaNbO3-(Bi0.5Li0.5)TiO3 lead-free relaxor ferroelectric capacitors with superior energy-storage performances via multiple synergistic design. Adv. Energy Mater. 11, 2101378 (2021). 10.1002/aenm.202101378

[60] [60] J. Jiang, X. Meng, L. Li, S. Guo, M. Huang et al., Ultrahigh energy storage density in lead-free relaxor antiferroelectric ceramics via domain engineering. Energy Storage Mater. 43, 383–390 (2021). 10.1016/j.ensm.2021.09.018

[61] [61] Q. Hu, X. Wei, Abnormal phase transition and polarization mismatch phenomena in BaTiO3-based relaxor ferroelectrics. J. Adv. Dielect. 9, 1930002 (2019). 10.1142/s2010135x19300020

[62] [62] F. Yan, K. Huang, T. Jiang, X. Zhou, Y. Shi et al., Significantly enhanced energy storage density and efficiency of BNT-based perovskite ceramics via A-site defect engineering. Energy Storage Mater. 30, 392–400 (2020). 10.1016/j.ensm.2020.05.026

[63] [63] X. Zhao, W. Bai, Y. Ding, L. Wang, S. Wu et al., Tailoring high energy density with superior stability under low electric field in novel (Bi0.5Na0.5)TiO3-based relaxor ferroelectric ceramics. J. Eur. Ceram. Soc. 40, 4475–4486 (2020). 10.1016/j.jeurceramsoc.2020.05.078

[64] [64] D. Li, Y. Lin, Q. Yuan, M. Zhang, L. Ma et al., A novel lead-free Na0.5Bi0.5TiO3-based ceramic with superior comprehensive energy storage and discharge properties for dielectric capacitor applications. J. Materiomics 6, 743–750 (2020). 10.1016/j.jmat.2020.06.005

[65] [65] H. Qi, R. Zuo, Linear-like lead-free relaxor antiferroelectric (Bi0.5Na0.5)TiO3–NaNbO3 with giant energy-storage density/efficiency and super stability against temperature and frequency. J. Mater. Chem. A 7, 3971–3978 (2019). 10.1039/C8TA12232F

[66] [66] H. Yang, F. Yan, Y. Lin, T. Wang, Novel strontium titanate-based lead-free ceramics for high-energy storage applications. ACS Sustain. Chem. Eng. 5, 10215–10222 (2017). 10.1021/acssuschemeng.7b02203

[67] [67] Y. Huang, L. Zhang, R. Jing, Q. Hu, D.O. Alikin et al., Thermal stability of dielectric and energy storage performances of Ca-substituted BNTZ ferroelectric ceramics. Ceram. Int. 47, 6298–6309 (2021). 10.1016/j.ceramint.2020.10.208

[68] [68] G. Liu, J. Dong, L. Zhang, L. Yu, F. Wei et al., Na0.25Sr0.5Bi0.25TiO3 relaxor ferroelectric ceramic with greatly enhanced electric storage property by a B-site ion doping. Ceram. Int. 46, 11680–11688 (2020). 10.1016/j.ceramint.2020.01.199

[69] [69] R. Kang, Z. Wang, X. Lou, W. Liu, P. Shi et al., Energy storage performance of Bi0.5Na0.5TiO3-based relaxor ferroelectric ceramics with superior temperature stability under low electric fields. Chem. Eng. J. 410, 128376 (2021). 10.1016/j.cej.2020.128376

[70] [70] G. Liu, L. Hu, Y. Wang, Z. Wang, L. Yu et al., Investigation of electrical and electric energy storage properties of La-doped Na0.3 Sr0.4Bi0.3TiO3 based Pb-free ceramics. Ceram. Int. 46, 19375–19384 (2020). 10.1016/j.ceramint.2020.04.280

[71] [71] L. Yu, J. Dong, M. Tang, Y. Liu, F. Wu et al., Enhanced electrical energy storage performance of Pb-free A-site La3+-doped 0.85Na0.5Bi0.5TiO3–0.15CaTiO3 ceramics. Ceram. Int. 46, 28173–28182 (2020). 10.1016/j.ceramint.2020.07.316

[72] [72] X. Zhang, D. Hu, Z. Pan, X. Lv, Z. He et al., Enhancement of recoverable energy density and efficiency of lead-free relaxor-ferroelectric BNT-based ceramics. Chem. Eng. J. 406, 126818 (2021). 10.1016/j.cej.2020.126818

[73] [73] X. Qiao, F. Zhang, D. Wu, B. Chen, X. Zhao et al., Superior comprehensive energy storage properties in Bi0.5Na0.5TiO3-based relaxor ferroelectric ceramics. Chem. Eng. J. 388, 124158 (2020). 10.1016/j.cej.2020.124158

[74] [74] F. Yan, X. Zhou, X. He, H. Bai, S. Wu et al., Superior energy storage properties and excellent stability achieved in environment-friendly ferroelectrics via composition design strategy. Nano Energy 75, 105012 (2020). 10.1016/j.nanoen.2020.105012

[75] [75] D. Hu, Z. Pan, X. Zhang, H. Ye, Z. He et al., Greatly enhanced discharge energy density and efficiency of novel relaxation ferroelectric BNT–BKT-based ceramics. J. Mater. Chem. C 8, 591–601 (2020). 10.1039/C9TC05528B

[76] [76] L. Yang, X. Kong, Z. Cheng, S. Zhang, Ultra-high energy storage performance with mitigated polarization saturation in lead-free relaxors. J. Mater. Chem. A 7, 8573–8580 (2019). 10.1039/c9ta01165j

[77] [77] T. Li, P. Chen, F. Li, C. Wang, Energy storage performance of Na0.5Bi0.5TiO3-SrTiO3 lead-free relaxors modified by AgNb0.85Ta0.15O3. Chem. Eng. J. 406, 127151 (2021). 10.1016/j.cej.2020.127151

[78] [78] Z. Jiang, H. Yang, L. Cao, Z. Yang, Y. Yuan et al., Enhanced breakdown strength and energy storage density of lead-free Bi05Na05TiO3-based ceramic by reducing the oxygen vacancy concentration. Chem. Eng. J. 414, 128921 (2021). 10.1016/j.cej.2021.128921

[79] [79] Z. Yang, H. Du, L. Jin, Q. Hu, H. Wang et al., Realizing high comprehensive energy storage performance in lead-free bulk ceramics via designing an unmatched temperature range. J. Mater. Chem. A 7, 27256–27266 (2019). 10.1039/C9TA11314B

[80] [80] G. Zhang, P. Liu, B. Fan, H. Liu, Y. Zeng et al., Large energy density in Ba doped Pb0.97La0.02(Zr0.65Sn0.3Ti0.05)O3 antiferroelectric ceramics with improved temperature stability. IEEE Trans. Dielectr. Electr. Insul. 24, 744–748 (2017). 10.1109/TDEI.2017.006161

[81] [81] L. Jin, W. Luo, L. Hou, Y. Tian, Q. Hu et al., High electric field-induced strain with ultra-low hysteresis and giant electrostrictive coefficient in Barium strontium titanate lead-free ferroelectrics. J. Eur. Ceram. Soc. 39, 295–304 (2019). 10.1016/j.jeurceramsoc.2018.09.005

[82] [82] H. Ye, F. Yang, Z. Pan, D. Hu, X. Lv et al., Significantly improvement of comprehensive energy storage performances with lead-free relaxor ferroelectric ceramics for high-temperature capacitors applications. Acta Mater. 203, 116484 (2021). 10.1016/j.actamat.2020.116484

[83] [83] A.K. Yadav, H. Fan, B. Yan, C. Wang, J. Ma et al., Enhanced storage energy density and fatigue free properties for 0.94Bi0.50(Na0.78K0.22)0.50Ti1−x(Al0.50Nb0.50)xO3–0.06BaZrO3 ceramics. Ceram. Int. 46, 17044–17052 (2020). 10.1016/j.ceramint.2020.03.292

[84] [84] A. Xie, H. Qi, R. Zuo, Achieving remarkable amplification of energy-storage density in two-step sintered NaNbO3–SrTiO3 antiferroelectric capacitors through dual adjustment of local heterogeneity and grain scale. ACS Appl. Mater. Interfaces 12, 19467–19475 (2020). 10.1021/acsami.0c00831

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Wenjing Shi, Leiyang Zhang, Ruiyi Jing, Yunyao Huang, Fukang Chen, Vladimir Shur, Xiaoyong Wei, Gang Liu, Hongliang Du, Li Jin. Moderate Fields, Maximum Potential: Achieving High Records with Temperature-Stable Energy Storage in Lead-Free BNT-Based Ceramics[J]. Nano-Micro Letters, 2024, 16(1): 091

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Paper Information

Category: Research Articles

Received: Jun. 30, 2023

Accepted: Nov. 16, 2023

Published Online: Jan. 23, 2025

The Author Email: Liu Gang (liugang13@swu.edu.cn), Du Hongliang (duhongliang@126.com), Jin Li (ljin@mail.xjtu.edu.cn)

DOI:10.1007/s40820-023-01290-4

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