Journal of Inorganic Materials, Volume. 37, Issue 1, 38(2022)

Selective Oxidation of Biomass over Modified Carbon Nitride Photocatalysts

Xuechen LIU*... Di ZENG, Yuanyi ZHOU, Haipeng WANG, Ling ZHANG and Wenzhong WANG |Show fewer author(s)
Figures & Tables(11)
Normalized decay of the transient photocurrent of PI (1:2) and PI (1:2)-120 samples
XRD patterns of samples prepared at different conditions
Mott-Schottky spectra (a, b), estimated bandgap based on UV-Vis diffuse reflectance (c), valence band position estimation based on VB XPS (d), schematic diagram of catalyst energy band position (e) of different samples
TEM images of sample PI (1:2) (a, b) and sample PI (1:2)-120 (c, d)
XPS spectra of different samples (C1s)(a-d), and structural illustration of PI sample (e) (different colors of C atoms correspond to XPS spectra)
(a) Comparison of absorbance of methanone after testing the superoxide radical reaction; (b) Comparison of the yields of OH; (c) Comparison of the yields of H2O2
O2-TPD (a), UV-Vis diffuse reflectance spectra (b) and photocurrent profiles (c) of different samples Colorful figures are available on website
Cycling experiments of PI(1 : 2)-120 catalyst
Nitrogen oxide radical detection and catalytic mechanism analysis
Possible structural changes in PI catalysts before and after H2O2 treatment and their possible mechanism for catalytic oxidation of HMF
  • Table 1. Experimental results of catalytic oxidation of HMF by different catalysts

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    Table 1. Experimental results of catalytic oxidation of HMF by different catalysts

    EntryCatalystCon./%Sel./%
    1[a]C3N462.813.5
    2[a]Melem69.912.4
    3[a]PI (1:1)72.416.4
    4[a]PI (2:1)94.63.4
    5[a]PI (1:2)72.019.3
    6[a]PI (1:1)-12014.757.3
    7[a]PI (1:2)-12022.367.8
    8[b]PI (1:2)-12053.396.2
    9[c]PI (1:2)85.99.7
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Xuechen LIU, Di ZENG, Yuanyi ZHOU, Haipeng WANG, Ling ZHANG, Wenzhong WANG. Selective Oxidation of Biomass over Modified Carbon Nitride Photocatalysts[J]. Journal of Inorganic Materials, 2022, 37(1): 38

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Paper Information

Category: EDITORIAL

Received: Apr. 20, 2021

Accepted: --

Published Online: Sep. 23, 2022

The Author Email: LIU Xuechen (xuechen1215@shu.edu.cn)

DOI:10.15541/jim20210262

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