Bulletin of the Chinese Ceramic Society, Volume. 42, Issue 4, 1437(2023)

Mechanism and Leaching Properties of Geopolymer-Based Multiphase Ceramics High-Level Radioactive Liquid Waste Form

LI Qiu1, ZHU Xiang1,2, GENG Haining3, LI Zonggang1,2, MA Haosen1,2, and CHEN Wei1
Author Affiliations
  • 1[in Chinese]
  • 2[in Chinese]
  • 3[in Chinese]
  • show less
    References(22)

    [9] [9] BELL J L, DRIEMEYER P E, KRIVEN W M. Formation of ceramics from metakaolin-based geopolymers. Part II: K-based geopolymer[J]. Journal of the American Ceramic Society, 2009, 92(3): 607-615.

    [10] [10] LIU X N, DING Y, LU X R. Immobilization of simulated radionuclide 90Sr by fly ash-slag-metakaolin-based geopolymer[J]. Nuclear Technology, 2017, 198(1): 64-69.

    [11] [11] FERNANDEZ-JIMENEZ A, MACPHEE D E, LACHOWSKI E E, et al. Immobilization of cesium in alkaline activated fly ash matrix[J]. Journal of Nuclear Materials, 2005, 346(2/3): 185-193.

    [12] [12] CHEN S, REN D, LIU L K, et al. Sintering of metakaolin-based Na/Ca-geopolymers and their immobilization of Cs[J]. Journal of the American Ceramic Society, 2019, 102(12): 7125-7136.

    [13] [13] CHLIQUE C, LAMBERTIN D, ANTONUCCI P, et al. XRD analysis of the role of cesium in sodium-based geopolymer[J]. Journal of the American Ceramic Society, 2015, 98(4): 1308-1313.

    [14] [14] JIA L Y, HE P G, JIA D C, et al. Immobilization behavior of Sr in geopolymer and its ceramic product[J]. Journal of the American Ceramic Society, 2020, 103(2): 1372-1384.

    [15] [15] LI L, XU Z H, LI H, et al. Immobilization of strontium and cesium by aluminosilicate ceramics derived from metakaolin geopolymer-zeolite A composites via 1 100 ℃ heating treatment[J]. Ceramics International, 2022, 48(11): 15236-15242.

    [19] [19] ASTM. Standard test method for static leaching of monolithic waste forms for disposal of radioactive waste: C1220-21[S]. America: ASTM International, 2021.

    [20] [20] NIU X B, ELAKNESWARAN Y, ISLAM C R, et al. Adsorption behaviour of simulant radionuclide cations and anions in metakaolin-based geopolymer[J]. Journal of Hazardous Materials, 2022, 429: 128373.

    [22] [22] HE P G, YANG Z H, YANG J L, et al. Preparation of fully stabilized cubic-leucite composite through heat-treating Cs-substituted K-geopolymer composite at high temperatures[J]. Composites Science and Technology, 2015, 107: 44-53.

    [24] [24] DING Y, JIANG Z D, XIONG T H, et al. Phase and microstructure evolution of 0.2Zr1-xCexO2/Zr1-yCeySiO4 (0≤x+y≤1) ceramics designed to immobilize tetravalent actinides[J]. Journal of Nuclear Materials, 2020, 539: 152318.

    [25] [25] SUN Y, YANG Q H, WANG H Q, et al. Depression of synthesis temperature and structure characterization of ZrSiO4 used in ceramic pigments[J]. Materials Chemistry and Physics, 2018, 205: 97-101.

    [26] [26] STEFANOVSKY S V, YUDINTSEV S V, NICKOLSKY M S, et al. Characterization of modified murataite based ceramics as a perspective hosts for actinides, fission, and corrosion products of HLW[J]. Journal of Nuclear Materials, 2020, 529: 151958.

    [27] [27] LUO J, LI X, ZHANG F J, et al. Sintering of monoclinic SrAl2Si2O8 ceramics and their Sr immobilization[J]. International Journal of Minerals, Metallurgy and Materials, 2021, 28(6): 1057-1062.

    [28] [28] PFAU A, SCHIERBAUM K D. The electronic structure of stoichiometric and reduced CeO2 surfaces: an XPS, UPS and HREELS study[J]. Surface Science, 1994, 321(1/2): 71-80.

    [29] [29] GREGG D J, FARZANA R, DAYAL P, et al. Synroc technology: perspectives and current status (review)[J]. Journal of the American Ceramic Society, 2020, 103(10): 5424-5441.

    [30] [30] ZHAO M Y, BIRKNER N, SCHAEPERKOETTER J, et al. Durable Cr-substituted (Ba,Cs)1.33(Cr,Ti)8O16 hollandite waste forms with high Cs loading[J]. Journal of the American Ceramic Society, 2022, 105(6): 4564-4576.

    [31] [31] WANG Y, WANG J, ZHANG X, et al. Order-disorder structural tailoring and its effects on the chemical stability of (Gd,Nd)2(Zr,Ce)2O7 pyrochlore ceramic for nuclear waste forms[J]. Nuclear Engineering and Technology, 2022, 54(7): 2427-2434.

    [32] [32] LAGO D C, SNCHEZ A D, PRADO M O. Cesium immobilization in porous silica and 137Cs self-heating simulations[J]. Journal of Nuclear Materials, 2022, 565: 153697.

    [33] [33] PAPYNOV E K, BELOV A A, SHICHALIN O O, et al. SrAl2Si2O8 ceramic matrices for 90Sr immobilization obtained via spark plasma sintering-reactive synthesis[J]. Nuclear Engineering and Technology, 2021, 53(7): 2289-2294.

    [34] [34] LI Z, CAO Y X, MAO X L, et al. In-situ immobilization of soil containing simulated radionuclide Ce using AC/CaCO3/nano-HAP by microwave sintering[J]. Journal of Radioanalytical and Nuclear Chemistry, 2021, 328(1): 315-323.

    [35] [35] FABIAN M, PINAKIDOU F, TOLNAI I, et al. Lanthanide (Ce,Nd,Eu) environments and leaching behavior in borosilicate glasses[J]. Scientific Reports, 2021, 11(1): 1-15.

    Tools

    Get Citation

    Copy Citation Text

    LI Qiu, ZHU Xiang, GENG Haining, LI Zonggang, MA Haosen, CHEN Wei. Mechanism and Leaching Properties of Geopolymer-Based Multiphase Ceramics High-Level Radioactive Liquid Waste Form[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(4): 1437

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category:

    Received: Dec. 6, 2022

    Accepted: --

    Published Online: Jun. 12, 2023

    The Author Email:

    DOI:

    Topics