Optics and Precision Engineering, Volume. 30, Issue 19, 2332(2022)
Strategy of improving mechanical stability of flexible perovskite solar cells
Fig. 1. (a) Schematic of a hexahedral element formed by infinite material division; (b-c) Schematic XRD configurations for the (b) out-of-plane and (c) in-plane measurement[11]; (d) Residual strain distribution in the depth of 50, 200, 500 nm for the tensile-strained film (measured (points) and Gauss fitted (line) diffraction strain data as a function of sin2
Fig. 2. Illustrations of perovskite solar cells (a1) without and (a2) with a protective layer consisting of a parylene film[27]; (b) The angular view SEM image of nanocone arrays of PDMS with aspect ratio of 0.5; (c) The angular view SEM image of i-cone arrays of epoxy with aspect ratio of 0.5; (d) Finite element mechanical modeling for perovskite solar cell based on flat and 0.5-aspect ratio-i-cone-epoxy substrates[28]
Fig. 3. (a) Dark-field optical microscopy image of the orthogonal AgNW arrays; The inset shows fast fourier transform image of orthogonal AgNW arrays. (b) An ultrathin and lightweight PSCs device mounted onto the surface of a leaf; (c) Variation in normalized device efficiency of PSCs using ITO and orthogonal AgNW electrodes under repeated (1 000 times) bending cycles[31]; (d) Device architecture of the all-carbon-electrode-based flexible PSCs; (e) PCE evolution of the flexible devices upon increasing bending curvature radius after 200 bending cycles; (f) Bending durability of the ITO/PEN-based and all-carbon-electrode-based flexible solar cells as a function of bending cycles (bending radius is fixed at 4 mm)[30]; (g) Resistance changes of PET/ITO and PET/IZVO TCEs during the dynamic fatigue twisting test with a fixed twisting angle of 20°; (h) Surface FESEM images of PET/ITO and PET/IZVO TCEs after the dynamic fatigue twisting; (i) XRD patterns of the IZO thin film and IZVO thin films deposited with varied concentration of V atoms on glass substrates; (j) Normalized PCE, (k)
Fig. 4. (a-d) The SEM images of CH3NH3PbI3-
Fig. 5. (a) Schematic illustration of grain boundary passivation of the perovskite film with s-ELA and its stitching effect for high mechanical endurance during stretch and release cycles; QNM-AFM characterization of MHP film (b) W/O s-ELA and (c) W/ s-ELA, with the corresponding (i) topography, (ii) Young’s modulus and (iii) adhesion images[37]; (d) The schematic diagram of PSCs structure of PEN/ITO/SnO2/Perovskite/Spiro-OMeTAD/MoO3/Ag and the enlarged illustration of the structure of borax as well as the interaction between borax and perovskite at grain boundaries; The indoor PCE decay curves of the pristine and target flexible devices (e) under different bending radii and (f) under different bending numbers with the bending radius of 5 mm[38]
Fig. 6. (a) Schematic diagram of the formation mechanism and working principle of the PEDOT:GO adhesive interface layer; (b) Viscosity tests at room temperature of different adhesive interface layer[40]; (c) Cross-sectional SEM image of FPSCs and schematic illustration of the device structure; (d) Normalized PCE for the FPSCs with different bending radii and the inset shows the corresponding photo of the cell under different bending radius; (e) PCE changes of FPSCs with or without Al(acac)3 boundary layer as a function of time (up to 1000 hours) under a working environment with relative humidity above 50%[41]
Fig. 7. Optical images of perovskite thin films containing different mass ratios of TUEG3 additives (a-b) before and (c-d) after annealing at 100 ℃ for 1 h; (e) Bending steps at a 1.5 mm radius, 50 times, and healing steps at 85 ℃ for 30 min. Solid lines represent median data, while dashed lines represent mean data[43]; (f) Supramolecular repair mechanism of the AD-23 adhesive; (g)
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Jieda CHEN, Dongdong LI, Xufei ZHU, Shanting ZHANG. Strategy of improving mechanical stability of flexible perovskite solar cells[J]. Optics and Precision Engineering, 2022, 30(19): 2332
Category: Micro/Nano Technology and Fine Mechanics
Received: Jun. 21, 2022
Accepted: --
Published Online: Oct. 27, 2022
The Author Email: ZHANG Shanting (zhangst@sari.ac.cn)