Journal of Inorganic Materials, Volume. 37, Issue 5, 554(2022)

Ruthenium-biocarbon Mimic Enzyme: Synthesis and Application in Colorimetric Detection of Pesticide Chlorpyrifos

Zhijun CAO and Zaijun LI*
Author Affiliations
  • School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
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    Figures & Tables(8)
    SEM (A), TEM (B), HRTEM images (C), and elemental mappings of Ru (D) and N (E) elements and XRD pattern (F) of the as-prepared Ru-biomass carbon composite
    Total XPS spectrum (A), high-resolution C1s (B), Ru3p (C) and N1s (D) XPS spectra of Ru-biomass carbon composite
    Absorption spectra of the reaction system catalysis by Ru-biomass carbon composite (a), CuO/Pt composite (b), Ru nanoparticles (c), and biomass carbon (d)
    Absorbances at 665 nm of the N2, air and O2 saturated TMB solutions with catalysis by Ru-biomass carbon composite
    Relationship curves of pH (A), reaction time (B), reaction temperature (C), and catalyst amount (D) with the absorbance of the reaction system
    Absorption spectra of the reaction system in the presence of 0, 10, 20, 30, 40, 50, 60, 70 and 80 ng/mL chlorpyrifos (A) and calibration plot of the absorbance at 665 nm varied with the chlorpyrifos concentration (B)
    • Table 1. Comparison of colorimetric methods with different nanozyme materials for detection of organophosphorus pesticides

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      Table 1. Comparison of colorimetric methods with different nanozyme materials for detection of organophosphorus pesticides

      Chromogenic systemAnalysis time/minLinear range/(ng·mL-1)Detection limit/(ng·mL-1)Ref.
      Gold nanoclusters401500-450006000[23]
      Acetylcholine5510000-1400004000[24]
      Cu-Ag/rGO30300-90001080[25]
      Hemin regulated by oligonucleotide622000-100000600[26]
      CuO/Pt50300-180000238.8[19]
      Fe-N-C76100-1000097[27]
      Cu NPs10300-300020.4[28]
      Ru-biomass carbon composite205-806.57This work
    • Table 2. Results for detection of chlorpyrifos in peach (n=5)

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      Table 2. Results for detection of chlorpyrifos in peach (n=5)

      SampleChlorpyrifos added/(ng·mL-1)Chlorpyrifos detected by proposed method/(ng·mL-1)Chlorpyrifos founded by GC-MS/(ng·mL-1)Recovery/%
      Honey peach0(5.9±0.15)(6.02±0.12)
      10.0(16.2±0.18)(16.05±0.10)101.8
      Nectarine0(9.98±0.07)(9.95±0.07)
      10.0(19.91±0.27)(20.1±0.27)99.6
      Peento0(4.96±0.11)(5.07±0.05)
      10.0(15.2±0.19)(15.07±0.25)101.6
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    Zhijun CAO, Zaijun LI. Ruthenium-biocarbon Mimic Enzyme: Synthesis and Application in Colorimetric Detection of Pesticide Chlorpyrifos[J]. Journal of Inorganic Materials, 2022, 37(5): 554

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Jun. 6, 2021

    Accepted: --

    Published Online: Jan. 10, 2023

    The Author Email: LI Zaijun (zaijunli@jiangnan.edu.cn)

    DOI:10.15541/jim20210365

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